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Unusual fragmentation of fulvene endoperoxides with phenyliodosyl bis(trifluoroacetate) (PIFA)
Date
2003-05-01
Author
Ozer, G
Saracoglu, N
Balcı, Metin
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Reaction of unsaturated fulvene endoperoxides with dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate gave saturated fulvene endoperoxides containing the 1,2-dihydropyridazine ring. Treatment of dihydropyridazine endoperoxides with water followed by phenyliodosyl bis(trifluoroacetate) oxidation provided acrylic acid derivatives and dimethyl pyridazine-3,6-dicarboxylate.
Subject Keywords
Organic Chemistry
URI
https://hdl.handle.net/11511/56405
Journal
JOURNAL OF HETEROCYCLIC CHEMISTRY
DOI
https://doi.org/10.1002/jhet.5570400319
Collections
Graduate School of Natural and Applied Sciences, Article