Unusual fragmentation of fulvene endoperoxides with phenyliodosyl bis(trifluoroacetate) (PIFA)

Date

2003-05-01

Author

Ozer, G
Saracoglu, N
Balcı, Metin

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Reaction of unsaturated fulvene endoperoxides with dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate gave saturated fulvene endoperoxides containing the 1,2-dihydropyridazine ring. Treatment of dihydropyridazine endoperoxides with water followed by phenyliodosyl bis(trifluoroacetate) oxidation provided acrylic acid derivatives and dimethyl pyridazine-3,6-dicarboxylate.

Subject Keywords

Organic Chemistry

URI

https://hdl.handle.net/11511/56405

Journal

JOURNAL OF HETEROCYCLIC CHEMISTRY

DOI

https://doi.org/10.1002/jhet.5570400319

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Graduate School of Natural and Applied Sciences, Article

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Citation Formats

G. Ozer, N. Saracoglu, and M. Balcı, “Unusual fragmentation of fulvene endoperoxides with phenyliodosyl bis(trifluoroacetate) (PIFA),” JOURNAL OF HETEROCYCLIC CHEMISTRY, pp. 529–533, 2003, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/56405.