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A phase diagram near the NAC* point in liquid crystals
Date
2000-01-01
Author
Salihoglu, S
Tublek, A
Yurtseven, Hasan Hamit
Metadata
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Wt study here a mean field model to obtain the phase diagram (concentration versus temperature) near the NAC* point in a binary mixture of liquid crystal. Wr have Fitted our phase line equations to the experimental data for the mixture of SCE9 + SCE10 liquid crystals. We deduce fi om our analysis that there should exist a tricritical point close to the NAC* point on the AC* phase line.
Subject Keywords
Instrumentation
,
General Materials Science
URI
https://hdl.handle.net/11511/56540
Journal
PHASE TRANSITIONS
DOI
https://doi.org/10.1080/01411590008244103
Collections
Department of Physics, Article
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Tublek, A; Yurtseven, Hasan Hamit; Salihoglu, S (Informa UK Limited, 1998-01-01)
In this study we have developed a mean-field model to obtain the phase diagram for a mixture of liquid crystals. Our mean-field model gives the phase diagram of the nematic, smectic A and smectic C phases near the NAC point. We have fitted our model to the experimentally observed data. From this fitting, we conclude that our mean-field model explains correctly the experimentally observed behavior of a mixed liquid crystalline system near the NAC point.
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We calculate here the phase line equations using the mean field theory for the liquid-solid I-solid II phases in the ammonia close to the melting point. Our calculated phase line equations have been fitted to the experimental data. Our calculated phase diagram agrees very well with the experimentally obtained P-T phase diagram from the literature.
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This study gives the predicted frequencies for the Raman modes of v(7)TA(56 cm(-1)), v(5)LO(177 cm(-1)) and v(2)(1684 cm(-1)) of NH4Br at various temperatures for zero pressure across the lambda-phase transition in this crystal system. We calculate the Raman frequencies by means of a constant mode Gruneisen parameter for each mode across the lambda-phase change region of NH4Br.
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In this study we have developed a mean field model to obtain the phase diagrams for NH4Cl and NH4Br. The phase diagrams obtained from our macroscopic theory are in good agreement with those obtained experimentally.
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S. Salihoglu, A. Tublek, and H. H. Yurtseven, “A phase diagram near the NAC* point in liquid crystals,”
PHASE TRANSITIONS
, pp. 263–276, 2000, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/56540.