Gold(I)/Zn(II) catalyzed tandem hydroamination/annulation reaction of 4-yne-nitriles

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2010-01-01

Author

Demir, Ayhan Sıtkı
Emrullahoglu, Mustafa
Buran, Kerem

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The tandem hydroamination-annulation reaction of 4-pentyne-nitriles in the presence of amine nucleophiles and a cooperatively operating catalyst system, consisting of Ph(3)PAuCl and Zn(ClO(4))(2), provides an efficient route to 2-aminopyrroles. Two regioisomeric 2-aminopyrroles were formed in moderate to good yields.

Subject Keywords

Materials Chemistry, Electronic, Optical and Magnetic Materials, General Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Catalysis

URI

https://hdl.handle.net/11511/62770

Journal

CHEMICAL COMMUNICATIONS

DOI

https://doi.org/10.1039/c0cc02357d

Collections

Department of Chemistry, Article

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Citation Formats

A. S. Demir, M. Emrullahoglu, and K. Buran, “Gold(I)/Zn(II) catalyzed tandem hydroamination/annulation reaction of 4-yne-nitriles,” CHEMICAL COMMUNICATIONS, pp. 8032–8034, 2010, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/62770.