Gold(I)/Zn(II) catalyzed tandem hydroamination/annulation reaction of 4-yne-nitriles

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2010-01-01
Demir, Ayhan Sıtkı
Emrullahoglu, Mustafa
Buran, Kerem
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The tandem hydroamination-annulation reaction of 4-pentyne-nitriles in the presence of amine nucleophiles and a cooperatively operating catalyst system, consisting of Ph(3)PAuCl and Zn(ClO(4))(2), provides an efficient route to 2-aminopyrroles. Two regioisomeric 2-aminopyrroles were formed in moderate to good yields.
Materials Chemistry, Electronic, Optical and Magnetic Materials, General Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Catalysis
https://hdl.handle.net/11511/62770
CHEMICAL COMMUNICATIONS
Department of Chemistry, Article

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Citation Formats
A. S. Demir, M. Emrullahoglu, and K. Buran, “Gold(I)/Zn(II) catalyzed tandem hydroamination/annulation reaction of 4-yne-nitriles,” CHEMICAL COMMUNICATIONS, pp. 8032–8034, 2010, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/62770.
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