Excimer emission and energy transfer in cofacial boradiazaindacene (BODIPY) dimers built on a xanthene scaffold

Date

2006-03-13

Author

Saki, N
Dinc, T
Akkaya, EU

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Using a rigid xanthene scaffold, a series of boradiazaindacene derivatives were synthesized. In some of these compounds, two boradiazaindacene derivatives were placed cofacially, resulting in significant inter-chromophoric interactions, including excimer emission. A simple modification of boradiazaindacene structure leads to formation of an ICT dye, which has distinct spectral properties. Energy transfer between two BODIPY dyes was demonstrated as well. In addition, the spectral properties of ICT dye can be modulated by the addition of the acid leading to an acid switchable, energy transfer cassette.

Subject Keywords

Molecular switches, Multichromophoric systems, Energy transfer, BODIPY dyes

URI

https://hdl.handle.net/11511/66191

Journal

TETRAHEDRON

DOI

https://doi.org/10.1016/j.tet.2005.12.021

Collections

Department of Chemistry, Article

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Citation Formats

N. Saki, T. Dinc, and E. Akkaya, “Excimer emission and energy transfer in cofacial boradiazaindacene (BODIPY) dimers built on a xanthene scaffold,” TETRAHEDRON, pp. 2721–2725, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/66191.