Catalytic asymmetric synthesis of pyrrolidine derivatives



Catalytic enantioselective addition of diethylzinc to aldehydes using aziridine based chiral ligands
BULUT, Adnan; ASLAN, Ayhan; İZGÜ, Enver Cagri; Doğan, Özdemir (Elsevier BV, 2007-05-16)
The readily available ferrocenyl substituted aziridinylmethanol 1 (FAM-1) was used as a chiral catalyst in the diethylzinc addition reaction to aromatic and aliphatic aldehydes to give secondary alcohols in high yields and up to 99% enantiomeric excess at room temperature. The catalyst can be recovered and used without losing its activity.
Catalytic partial oxidation of methane to formaldehyde
Akbulut, Barış; Önal, Işık; Department of Chemical Engineering (2000)
Catalytic asymmetric nitroaldol (Henry) reaction with a zinc-Fam catalyst
Bulut, Adnan; Aslan, Ayhan; Doğan, Özdemir (American Chemical Society (ACS), 2008-09-19)
Ferrocenyl-substituted aziridinylmethanol (Fam-1) was used as a catalyst with zinc for the asymmetric nitroaldol (Henry) reaction. This catalyst worked with a variety of aldehydes (aromatic, aliphatic, alpha,beta-unsaturated, and heteroaromatic) and alpha-ketoesters to give the nitroaldol product in up to 97% yield and 91% ee. The chiral ligand call be recovered and recycled Without losing its activity.
Catalytic degradation of polypropylene over alumina loaded mesoporous catalysts
Obali, Zeynep; Sezgi, Naime Aslı; Doğu, Timur (2012-10-01)
The catalytic thermal degradation of polypropylene over aluminum containing ordered mesoporous MCM-41 and SBA-15 based materials was studied in a semi-batch reactor. Heavier molecules degraded to lighter hydrocarbons in the presence of catalysts and they gave high ethylene selectivity among the gaseous products. Additionally, butane selectivity increased with the use of catalysts. SBA-type catalysts showed higher selectivity to lighter hydrocarbons (<C-14). C-7 selectivity among the liquid products was high...
Catalytic conversion of methane to methanol on Cu-SSZ-13 using N2O as oxidant
İpek Torun, Bahar (2016-01-01)
Direct catalytic methanol production from methane is achieved on Cu-SSZ-13 zeolite catalysts using N2O as the oxidant. The methanol production rate on Cu-SSZ-13 (on a per gram basis) was more than twice the rate on Cu-mordenite and more than four times the rate on Cu-ZSM-5.
Citation Formats
Ö. Doğan, “Catalytic asymmetric synthesis of pyrrolidine derivatives,” Fas, 2017, vol. 2017, p. 62, Accessed: 00, 2021. [Online]. Available: