Catalytic enantioselective addition of diethylzinc to aldehydes using aziridine based chiral ligands

Date

2007-05-16

Author

BULUT, Adnan
ASLAN, Ayhan
İZGÜ, Enver Cagri
Doğan, Özdemir

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The readily available ferrocenyl substituted aziridinylmethanol 1 (FAM-1) was used as a chiral catalyst in the diethylzinc addition reaction to aromatic and aliphatic aldehydes to give secondary alcohols in high yields and up to 99% enantiomeric excess at room temperature. The catalyst can be recovered and used without losing its activity.

Subject Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Catalysis

URI

https://hdl.handle.net/11511/39220

Journal

TETRAHEDRON-ASYMMETRY

DOI

https://doi.org/10.1016/j.tetasy.2007.04.013

Collections

Department of Chemistry, Article

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Citation Formats

A. BULUT, A. ASLAN, E. C. İZGÜ, and Ö. Doğan, “Catalytic enantioselective addition of diethylzinc to aldehydes using aziridine based chiral ligands,” TETRAHEDRON-ASYMMETRY, pp. 1013–1016, 2007, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/39220.