HEXABROMOCYCLODODECANE (HBCDD) BIODEGRADATION IN ANAEROBIC SEDIMENT MESOCOSMS

Date

2018-06-27

Author

Karahan, İrem
Demirtepe, Hale
İmamoğlu, İpek

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https://hdl.handle.net/11511/74167

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HEXACHLOROCYCLOPENTADIENE IN DIELS-ALDER ASYMMETRIC REACTION AKHMEDOV, IM; PEYNIRCIOGLU, B; MAMEDOV, EG; Tanyeli, Cihangir; DEMIR, AS (1994-02-14) Asymmetric thermal Diels-Alder reactions with chiral dienophiles l-menthyl acrylate and l-menthyl allyl ether, using hexachlorocyclopentadiene (HCC) gave cycloadducts of up to 15%ee. Milder reaction conditions achieved by the use of Lewis acid catalysis increased the optical yields up to 2.8 fold. The catalyzed and uncatalyzed reactions using l-menthyl acrylate result in the formation of adducts having opposite configurations. The products have also been resolved via diastereomer formation as pure enantiomers.
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Citation Formats

İ. Karahan, H. Demirtepe, and İ. İmamoğlu, “HEXABROMOCYCLODODECANE (HBCDD) BIODEGRADATION IN ANAEROBIC SEDIMENT MESOCOSMS,” 2018, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/74167.