Hydrogen-bonded Multilayers of Tannic Acid: Tuning pH Response

2007-02-05

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We report on association of tannic acid (TA) with neutral or charged polymers in solution and at surfaces and contrast hydrogen-bonded and electrostatically associated polymer/TA complexes and TA/polymer layer-by-layer (LbL) films as per their stability in the pH scale. The neutral polymers used for hydrogen bonding with TA were poly(N-vinylcaprolactam) (PVCL), poly(N-vinylpyrrolidone) (PVPON), poly(ethylene oxide) (PEO), or poly(N-isopropylacrylamide) (PNIPAM), and the polymer used to explore electrostatic...
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We report on incorporation of coordination complexes into hydrogen-bonded multilayers which was found to be an effective method to control pH-induced disintegration kinetics of hydrogen-bonded multilayers. By taking advantage of the strong metal chelating and hydrogen donating properties of Tannic Acid (TA), coordination complexes of Zr4+ and TA (Zr(IV)-TA complexes) were prepared and then self-assembled at the surface using hydrogen accepting polymers such as poly (N-vinyl caprolactam) (PVCL) or poly(N-iso...
Citation Formats
İ. Erel Göktepe, “Hydrogen-bonded Multilayers of Tannic Acid: Tuning pH Response,” 2007, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/81125.