Maximizing the performance of single and multijunction MA and lead-free perovskite solar cell

Date

2021-06-01

Author

Azadinia, M.
Ameri, Mohsen
Ghahrizjani, R.T.
Fathollahi, M.

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

358
views

0
downloads

Finding a highly stable and appropriate perovskite solar cell with optimum design parameters is crucial for being included as the top cell in tandem structure, with Si as the bottom cell, to realize the power conversion efficiencies (PCEs) over the limits imposed by Shockley-Queisser theory. Here, we quantize the performance of methylammonium (MA) and lead (Pb)-free all-inorganic cesium tin-germanium triiodide (CsSnxG1-xI3) by combining CsSnI3 (Eg = 1.31 eV) and CsGeI3 (Eg = 1.63 eV) perovskites for standalone and integrated multijunction structure in tandem with Silicon solar cell. The maximum PCE of the standalone cell is shown to be about 16.5% and 13.6% for n-i-p and p-i-n structures, respectively, almost twice the present PCE value obtained in the experiment. Optimum perovskite absorber bandgap of 1.38 eV and electron affinity of 4eV with composition ratio of X = 0.25 (CsSn1-xGexI3) in both n-i-p and p-i-n structures are obtained. The optimum perovskite absorber thickness of 600 nm leads to the highest PCEs. The effect of doping concentration and defect density on absorber was also explored. Finally, four-terminal and six-terminal tandem solar cells are designed and optimized. With CsSn1-xGexI3 perovskite thickness of 385 nm and bandgap of 1.56 eV in the four-terminal, it demonstrates the high PCE of 26.9%. Interestingly, with FASnI2Br (Eg = 1.68 eV and thickness = 200 nm) and CsSn0.75Ge0.25I3 (Eg = 1.38 eV and thickness = 200 nm) as the absorber layer of the top cell and middle cell in the six-terminal PSC, respectively, the superior PCE of 27.8% is realized for MA and Pb-free six-terminal perovskite/Si tandem solar cell. This work provides a route toward the development of highly stable all-inorganic perovskite/Si tandem solar cells.

Subject Keywords

Perovskite solar cell, Methyl ammonium and lead- free, Multijunction tandem solar cell

URI

https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85102406155&origin=inward
https://hdl.handle.net/11511/90831

Journal

Materials Today Energy

DOI

https://doi.org/10.1016/j.mtener.2021.100647

Collections

Center for Solar Energy Research and Applications (GÜNAM), Article

Suggestions

OpenMETU
Core

Metal-Free Interconnecting Layer for Monolithic Perovskite/Organic Tandem Solar Cells with Enhanced Outdoor Stability Xu, Han; Merino, Luis Torres; Koc, Mehmet; Aydin, Erkan; Zhumagali, Shynggys; Haque, Md Azimul; Yazmaciyan, Aren; Sharma, Anirudh; Villalva, Diego Rosas; Hernandez, Luis Huerta; De Bastiani, Michele; Babics, Maxime; Isikgor, Furkan H.; De Wolf, Stefaan; Yerci, Selçuk; Troughton, Joel; Baran, Derya (2022-11-28) Photovoltaics with monolithically connected tandem architectures have the potential to achieve high efficiencies owing to enhanced spectral absorption and reduced thermal losses. To achieve this, photoactive layers with complementary absorption and interconnecting layers, which are robust, transparent, and energetically suitable, are essential. Here, we investigate a strategy to create an efficient, highly transparent, ohmic, and chemically robust interconnecting layer based on atomic layer-deposited tin ox...
Selective emitter formation via single step doping through laser patterned mask oxide layer for monocrystalline silicon solar cells Çiftpınar, Emine Hande; Turan, Raşit; Department of Physics (2014) Selective emitter is one of the new approaches for higher efficiency solar cells. Although selective emitter cells could be processed by several different methods such as; etch back process, laser doping, ion implantation, doping paste, a different method based on diffusion through a laser patterned oxide layer was studied in this thesis. Utilization of pattern oxide layer as a diffusion barrier enables to obtain selective emitter profile via single step doping which reduces overall production cost and time...
Optimization of laser processing for PERC type c-Si solar cells Genç, Ezgi; Turan, Raşit; Department of Micro and Nanotechnology (2019) Passivated Emitter Rear Contact (PERC) type solar cells, which currently owns a similar market share as the standard type solar cells, is expected to be the dominant type of the photovoltaic (PV) market in near future (ITRPV, 2019) due to its high performance/cost ratio. Hence, it is critical to optimize PERC process steps to achieve higher efficiencies. In PERC concept, the stack of a passivation layer and SiNx capping layer is locally ablated to form low recombination and low resistive contacts. In this w...
Dual-band high-frequency metamaterial absorber based on patch resonator for solar cell applications and its enhancement with graphene layers Ustunsoy, Mehmet Pasa; Sabah, Cumali (2016-12-05) In this paper, a dual-band high-frequency metamaterial absorber based on patch resonator is designed and analyzed for solar cells. In order to obtain a metamaterial absorber, metal-semiconductor-metal layers are combined. The results of the designed structure are shown in the infrared and visible ranges of solar spectrum. Structural parameters and dimensions of the device have a significant importance on the performance of the designed absorber. The simulations are carried out with full-wave electromagnetic...
CZTSSe thin film : growth, characterization and solar cell applications Terlemezoğlu, Makbule; Parlak, Mehmet; Department of Physics (2019) Cu2ZnSn(S,Se)4 (CZTSSe) compound is one of the most promising absorber materials for thin film solar cell technology due to the abundance and non-toxicity of its constituents. Besides, CZTSSe has an ideal direct band gap value in the range of 1-1.5 eV and high absorption coefficient (> 104 cm-1) in the visible region, which satisfies the conversion of the maximum amount of energy of the solar spectrum. For this, CZTSSe absorber layer with only a few microns of thickness is sufficient to absorb all the photo...

Citation Formats

M. Azadinia, M. Ameri, R. T. Ghahrizjani, and M. Fathollahi, “Maximizing the performance of single and multijunction MA and lead-free perovskite solar cell,” Materials Today Energy, pp. 0–0, 2021, Accessed: 00, 2021. [Online]. Available: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85102406155&origin=inward.