Microstructural and dielectric properties of naphthalene based polyamide/β-Ni(OH)2 nanocomposites

Date

2018-01-01

Author

Sezer, Selda
Öz, Erdinc
ALTIN, SERDAR
Vural, Sema
GÜLTEK, AHMET
KÖYTEPE, SÜLEYMAN
Nilüfer Kıvılcım, F.

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Background: Aromatic polyamides are important materials having outstanding thermal, electronic and mechanical properties among high performance polymers and industrial plastics. In addition, aromatic polyamides can be utilized in electronic devices with their low dielectric constant which indicates the storage capacity of these devices. Objective: Free volume is very important for dielectric materials and increase in free volume of a polymer reduces its dielectric constant. The aims of the current study are to create free volume in the bulk polyamide structure and to reduce the dielectric constant by using β-Ni(OH)2 particles. Method: The composites obtained from β-Ni(OH)2 (flower-like nanoparticles) in a naphthalene-based polyamide matrix were prepared. Firstly, β-Ni(OH)2 nanoparticles were synthesized by microwave-assisted solvothermal technique under various reaction conditions. Then, polyamide/β-Ni(OH)2 composites were prepared via direct dispersion methods at different reinforcement ratios. Results: β-Ni(OH)2 (flower-like nanoparticles) and polyamide/β-Ni(OH)2 composites were prepared successfully. Our studies showed that the dispersion of β-Ni(OH)2 nanoparticles in polyamide matrix is homogenous and prepared composites have good thermal and dielectric properties with promising results for electronic industry. Conclusion: Dielectric properties of the prepared composites decrease with increasing β-Ni(OH)2 nanoparticle content and all composites show low dielectric constant when β-Ni(OH)2 nanoparticle content is over 1 wt.% compared to the pure polyamide.

Subject Keywords

Aromatic polyamides, Dielectric constant, Dielectric properties, Nanocomposite, Polyamide, β-Ni(OH)2

URI

https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85053824513&origin=inward
https://hdl.handle.net/11511/96990

Journal

Micro and Nanosystems

DOI

https://doi.org/10.2174/1876402910666180620162121

Collections

Department of Chemical Engineering, Article

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Citation Formats

S. Sezer et al., “Microstructural and dielectric properties of naphthalene based polyamide/β-Ni(OH)2 nanocomposites,” Micro and Nanosystems, vol. 10, no. 1, pp. 47–56, 2018, Accessed: 00, 2022. [Online]. Available: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85053824513&origin=inward.