Temporal variation in aerosol composition at northwestern Turkey

Date

2013

Author

Genç Tokgöz, D. Deniz

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Daily aerosol samples (PM) were collected at a rural station, which is 5 km away from the Turkish-Bulgarian border between April 2006 and March 2008. Aerosol samples were analyzed for elements by ICPMS, ions by IC and black carbon by aethalometer to provide a multi-species aerosol data set, which can represent aerosol population for Northwestern Turkey and Eastern Europe. Average concentration of SO42-, NO3- and NH4+ was 5.8, 2.9 and 2.0 μg m-3, respectively, while total aerosol mass was 66 μg m-3. Seasonal variation of crustal species had maxima in summer, while most of the anthropogenic species had maxima in winter. Rainfall was found as the only local meteorological parameter affecting aerosols concentrations. The dominant sectors of air masses arriving the Northwestern Turkey were northeast in summer and west-northwest in winter. Air masses were classified into five clusters regarding their wind speed and direction. Most species indicated significant differences between clusters. The influence of forest fires in Ukraine and Russian Federation was identified by cluster analysis using soluble K as tracer. Source apportionment of PM was carried out by EPA PMF model and five sources were resolved. Crustal emissions were found to be the major contributor to PM (41%). The second largest source was distant anthropogenic sources with a contribution of 26%. Traffic was also a remarkable source with 16% contribution. Sea salt and stationary combustion sources accounted for 9% and 8% of PM, respectively. Potential source regions of resolved sources were determined by potential source contribution function (PSCF).

Subject Keywords

Air masses., Cluster analysis., Atmospheric circulation., Aerosols., Environmental impact analysis.

URI

http://etd.lib.metu.edu.tr/upload/12615740/index.pdf
https://hdl.handle.net/11511/22623

Collections

Graduate School of Natural and Applied Sciences, Thesis