Micromechanical modeling of carbon nanotube – polymer composites

Download
2018
Taç, Vahidullah
A micromechanics-based model is developed to simulate carbon nanotube – polymer nanocomposites and analyze its mechanical behavior. The nanocomposite is first divided into four distinct regions, or phases, based on mechanical behavior and density; the carbon nanotube, the interface, the interphase and the polymer. The finite element method was later used to combine the nanotube and interface phases into an effective fiber for better representation and incorporation of their roles and constitutive properties in the micromechanical model. The elastic moduli of the interphase were modelled in a position dependent manner to better represent its true nature. Parametric studies were performed on the model and the results were compared with the previous work in the literature. The four phases were each found to have significant effects on the behavior of the nanocomposite. It was observed that when a soft interface model is used, the direct effect of the carbon nanotube on the stiffness of the nanocomposite vanishes, and the interphase becomes the sole reinforcement phase in the composite. Whereas in the case of a stiff interface the CNT significantly affects the mechanical properties of the composite through the effective fiber. Thinner but longer carbon nanotubes were found to better enhance the stiffness of the nanocomposite compared to thick and short nanotubes.

Suggestions

Micromechanical Modelling of Carbon Nanotube Reinforced Composite Materials with a Functionally Graded Interphase
Gülaşık, Hasan; Göktepe, Serdar; Gürses, Ercan (null; 2018-10-10)
This paper introduces a new method of determining the mechanical properties of carbon nanotube-polymer composites using a multi-inclusion micromechanical model with functionally graded phases. The nanocomposite was divided into four regions of distinct mechanical properties; the carbon nanotube, the interface, the interphase and bulk polymer. The carbon nanotube and the interface were later combined into one effective fiber using a finite element model. The interphase was modelled in a functionally graded m...
Micromechanical modelling of carbon nanotube reinforced composite materials with a functionally graded interphase
Taç, Vahidullah; Gürses, Ercan (SAGE Publications, 2019-12-01)
This paper introduces a new method of determining the mechanical properties of carbon nanotube-polymer composites using a multi-inclusion micromechanical model with functionally graded phases. The nanocomposite was divided into four regions of distinct mechanical properties; the carbon nanotube, the interface, the interphase and bulk polymer. The carbon nanotube and the interface were later combined into one effective fiber using a finite element model. The interphase was modelled in a functionally graded m...
Micromechanical characterization of metallic glass — crystalline nanocomposite coatings
Abboud, Mohammad; Özerinç, Sezer; Kalay, Yunus Eren; Department of Micro and Nanotechnology (2018)
Amorphous/crystalline nanolayers provide an effective model system to study the mechanical behavior and size effects of metallic glasses and crystalline metals in confined geometries. They also provide an advantageous structure for improving the ductility of amorphous metals while maintaining their outstanding strength. Combination of high strength and ductility make these nanocomposites promising materials as wear resistant coatings. The structure-property relationship in Amorphous/Crystalline nanolayers c...
Electrochemical sensing of glucose using conjugated polymer/chitosan/mwcnt architecture
Özel, Hande; Toppare, Levent Kamil; Söylemez, Saniye; Department of Polymer Science and Technology (2018)
In this thesis an amperometric biosensor consisting of a conjugated polymer, chitosan and multi-walled carbon nanotubes constructed for the detection of glucose. Conjugated polymers have opened a new era for the development of biosensing platforms with their unique electronic properties, high stabilities and processabilities. They serve both as immobilization matrices for biorecognition elements and as transducers in biosensing devices. As an additional modification material, chitosan was participated in th...
Modelling and analyis of multı-walled carbon nanotube reinforced polymer composites
Fatima, Bushra; Esat, Volkan; Sustainable Environment and Energy Systems (2016-8)
In this study, multi-walled carbon nanotubes (MWNTs) and multi walled carbon nanotube reinforced epoxy composites (CNTRPs) are investigated by means of computational modelling. To begin with, individual tubes of MWNTs are modelled with varying chiralities through equivalent continuum modelling in order to examine their essential mechanical properties including Young’s modulus, shear modulus, and Poisson’s ratio. The finite element models developed incorporate beam elements that represent Carbon-Carbon ...
Citation Formats
V. Taç, “Micromechanical modeling of carbon nanotube – polymer composites,” M.S. - Master of Science, Middle East Technical University, 2018.