Stibine preconcentration in a quartz trap with subsequent atomization in the quartz multiatomizer for atomic absorption spectrometry

Date

2004-02-01

Author

Korkmaz, D
Dedina, J
Ataman, Osman Yavuz

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A preliminary evaluation of a simple (bare) quartz tube trap for collection of SbH3 and for volatilization of trapped analyte with subsequent atomization in a multiple microflame quartz tube atomizer (multiatomizer) for atomic absorption spectrometry is presented. The influence of relevant experimental parameters on the collection/volatilization efficiency was investigated. The parameters studied Were: collection temperature and time, volatilization temperature and flow rates of air and hydrogen for the volatilization. Under optimized conditions, the collection/volatilization efficiency was 65%. For the collection time of 120 s (sample volume of 8 ml), the detection limit was 3.9 pg ml(-1), and the analytical plot was linear up to 1.25 ng ml(-1). Possible ways of improving the performance of the set-up as well as the collection/volatilization efficiency are suggested.

Subject Keywords

Sb, AAS, Coil, Elements, Selenium, Tube, Multiple microflame, Graphite-furnace, Hydride generation, Nickel tetracarbonyl generation

URI

https://hdl.handle.net/11511/31095

Journal

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY

DOI

https://doi.org/10.1039/b308883a

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

D. Korkmaz, J. Dedina, and O. Y. Ataman, “Stibine preconcentration in a quartz trap with subsequent atomization in the quartz multiatomizer for atomic absorption spectrometry,” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, pp. 255–259, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/31095.