Speciation and preconcentration of inorganic tellurium from waters using a mercaptosilica microcolumn and determination by hydride generation atomic absorption spectrometry

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2000-12-01

Author

Korez, A
Eroglu, AE
Volkan, Mürvet
Ataman, Osman Yavuz

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A separation-preconcentration method utilising a mercapto-modified silica microcolumn was developed for the determination of trace amounts of Te(rv) and Te(VI) in waters by hydride generation atomic absorption spectrometry. Bottled drinking water, tap water and sea-water samples were spiked with sub-ng ml(-1) concentrations of Te(IV) and the spiked solutions were subjected to the mercapto-modified silica microcolumn separation and enrichment procedure. The spike recovery values varied between 86 and 114%. In addition to spike recovery experiments, accuracy was also verified via the analysis of a certified reference material. The limit of detection for Te(nt) in sea-water with a preconcentration factor of 50 was 0.037 ng ml(-1). The capability of the microcolumn enrichment scheme for on-line sample processing via flow manifolds was demonstrated. A detailed interference study was performed.

Subject Keywords

Plasma-mass spectrometry, Modified silica-gel, Graphite-furnace, Emission-spectrometry, Environmental-samples, Reductive coprecipitation, Selenium determination, Pre-concentration, Forming elements, Antimony

URI

https://hdl.handle.net/11511/31385

Journal

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY

DOI

https://doi.org/10.1039/b004696p

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

A. Korez, A. Eroglu, M. Volkan, and O. Y. Ataman, “Speciation and preconcentration of inorganic tellurium from waters using a mercaptosilica microcolumn and determination by hydride generation atomic absorption spectrometry,” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, pp. 1599–1605, 2000, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/31385.