Sulfated zirconia in SBA-15 structures with strong Bronsted acidity as observed by H-1 MAS NMR spectroscopy

Date

2007-05-01

Author

Yılmaz, Ayşen
Yılmaz, Aysun
Üner, Deniz

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In order to prepare high surface area highly acidic catalysts, different weight loadings of ZrO2 were incorporated in the SBA-15 structures which are subsequently sulfated by treating in 0.25 M H2SO4. The catalysts were characterized by means of TEM, XRD, N-2 adsorption, and H-1 MAS NMR. Bronsted type acidities of sulfated zirconia included SBA-15 materials were identified by a sharp H-1 MAS NMR line at 10.6 ppm. The highest acidity was obtained in the 25 mol% ZrO2 included SBA-15 catalyst with a BET surface area of 246 m(2)/g.

Subject Keywords

Sulfated zirconia, Super acid catalysts, H-1 MAS NMR, SBA-15, Mesoporous silica

URI

https://hdl.handle.net/11511/32296

Journal

CATALYSIS LETTERS

DOI

https://doi.org/10.1007/s10562-007-9078-9

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

A. Yılmaz, A. Yılmaz, and D. Üner, “Sulfated zirconia in SBA-15 structures with strong Bronsted acidity as observed by H-1 MAS NMR spectroscopy,” CATALYSIS LETTERS, pp. 79–85, 2007, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/32296.