Manganese(III) acetate based tandem oxidation of various cyclic β-alkoxy α,β-unsaturated ketones

Date

2000-10-07

Author

Tanyeli, Cihangir

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We describe the unusual preliminary results of manganese(III) acetate based tandem oxidation of various β-alkoxy 2-cyclopentenone and 2-cyclohexenone derivatives to afford corresponding α′-acetoxy-α′-phenyl substituted oxidation products in good yields.

Subject Keywords

Organic Chemistry, Biochemistry, Drug Discovery

URI

https://hdl.handle.net/11511/35832

Journal

Tetrahedron Letters

DOI

https://doi.org/10.1016/s0040-4039(00)01374-5

Collections

Department of Chemistry, Article

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Manganese(III) acetate based tandem oxidation of various α and β-alkoxy α,β-unsaturated ketones Tanyeli, Cihangir; Sezen, Bengü (Elsevier BV, 2002-12-09) We described the unusual results of manganese(III) acetate based tandem oxidation of various alpha and beta-alkoxy alpha,beta-unsaturated ketones to afford the corresponding alpha'-acetoxy-alpha'-phenyl substituted oxidation products in good yields. The tandem oxidation to monoacetoxylation ratio can be tuned by the amount of manganese(III) acetate.
Manganese(III) acetate promoted acetoxylation of various α,β-unsaturated cyclopentanones Tanyeli, Cihangir; Turkut, Engin; SEZEN, Bengü (Elsevier BV, 2003-02-10) We describe the results of manganese(III) acetate based regioselective oxidation of various alpha,beta-unsaturated cyclopentanones leading to alpha'-acetoxy alpha,beta-unsaturated cyclopentanones in good yields. Products due to monophenyl and diphenyl substituted dimerization have been identified as byproducts of the reaction.
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Citation Formats

C. Tanyeli, “Manganese(III) acetate based tandem oxidation of various cyclic β-alkoxy α,β-unsaturated ketones,” Tetrahedron Letters, pp. 7973–7976, 2000, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35832.