Enhancing electrochromic and kinetic properties of poly(2,3-bis(4-tert-butylphenyl)-5,8-di(1H-pyrrol-2-yl) quinoxaline) by copolymerization

Date

2010-02-28

Author

Celebi, Selin
Baran, Derya
Balan, Abidin
Toppare, Levent Kamil

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

186
views

0
downloads

Electrochemical copolymerization was utilized to combine several properties into a single material in order to obtain a highly stable polymer with a low band gap to meet the requirements for color variation. In that sense, two new donor acceptor type electrochromic copolymers of 2,3-bis(4-tert-butylphenyl)5,8-di(1H-pyrrol-2-yl) quinoxaline (TBPPQ) with bis(3,4-ethylenedioxythiophene) (BiEDOT) and with 4,7-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2-dodecyl-2H-benzo [ 1,231 triazole (BEBT) were synthesized by electrochemical polymerization. Polymers revealed multicolor electrochromic properties with distinct accessible states and low operation potentials. Electrochromic and kinetic properties of polymers were investigated using cyclic voltammetry (CV) and in situ UV-vis-NIR spectroscopy.

Subject Keywords

Electrochemistry, General Chemical Engineering

URI

https://hdl.handle.net/11511/36007

Journal

ELECTROCHIMICA ACTA

DOI

https://doi.org/10.1016/j.electacta.2009.12.010

Collections

Department of Chemistry, Article

Suggestions

OpenMETU
Core

Use of a thiophene-based conducting polymer in microbial biosensing ODACI DEMİRKOL, DİLEK; Kayahan, Senem; TİMUR, SUNA; Toppare, Levent Kamil (Elsevier BV, 2008-05-01) Immobilization of whole viable Pseudomonas fluorescens cells was achieved on a graphite electrode modified with a thiophene-based conducting polymer. Microbial electrodes were constructed by the entrapment of bacterial cells on conducting copolymer matrix using a dialysis membrane. The biosensor was characterized using glucose as the substrate. As well as analytical characterization, effects of electropolymerization time, pH and temperature on the sensor response were examined. Finally, operational stabilit...
Coaxial silver nanowire network core molybdenum oxide shell supercapacitor electrodes Yuksel, Recep; Coskun, Sahin; Ünalan, Hüsnü Emrah (Elsevier BV, 2016-03-01) We present a new hybrid material composed of molybdenum (IV) oxide (MoO2) shell on highly conducting silver nanowire (Ag NW) core in the network form for the realization of coaxial Ag NW/MoO2 nanocomposite supercapacitor electrodes. Ag NWs were simply spray coated onto glass substrates to form conductive networks and conformal MoO2 layer was electrodeposited onto the Ag NW network to create binder-free coaxial supercapacitor electrodes. Combination of Ag NWs and pseudocapacitive MoO2 generated an enhanced e...
Synthesis and spectroelectrochemical characterization of multi-colored novel poly(3,6-dithienylcarbazole) derivatives containing azobenzene and coumarin chromophore units Yigit, Deniz; Hacioglu, Serife O.; GÜLLÜ, Mustafa; Toppare, Levent Kamil (Elsevier BV, 2016-04-01) Azobenzene and coumarin units bearing four novel 3,6-linked thiophene-carbazole-thiophene type electroactive monomers were synthesized in order to observe the effects of strong chromophore units on the electrochemical and spectroelectrochemical behaviors of resulting pi-conjugated conducting polymers (PTCbzAz, PECbzAz, PTCbzCo and PECbzCo). Electronic and optoelectronic properties of all polymers were investigated by cyclic voltammetry and in situ spectroelectrochemical studies, and their oxidation potentia...
A novel electrochromic and fluorescent polythienylpyrrole bearing 1,1 '-bipyrrole CİHANER, ATİLLA; Mert, Olcay; Demir, Ayhan Sıtkı (Elsevier BV, 2009-01-30) A novel conducting polymer was successfully synthesized via electropolymerization of 1-(1H-pyrrol-1-yl)-2,5-di(thiophen-2-yl)-1H-pyrrole. The electrochemical and electro-optical properties of the corresponding polymer, which was the first example of polymer containing 1,1'-bipyrrole units, were elaborated using electroanalytical and spectroscopic techniques. Cyclic voltammograms and electro-optical studies showed that the polymer has a stable and well-defined reversible redox process as well as electrochrom...
Synthesis and polymerization of 2-and 3-substituted thiophene derivatives linked by polyether bridges Tirkeş, Süha; Önal, Ahmet Muhtar (Elsevier BV, 2004-11-15) New compounds consisting of 2- and 3-thienyl units linked by polyether bridges have been synthesized and their electrochemical polymerization was performed via constant potential electrolysis (CPE) in an electrolytic solution containing 0.1 M tetrabutylammonium hexafluorophosphate (TBAPF(6)) dissolved in CH3CN. 2-Thienyl monomers (I and II), but not 3-thienyl monomers (III and IV), were also polymerized via chemical oxidation, which yielded broken pi-conjugated polymer products. The polymers were characteri...

Citation Formats

S. Celebi, D. Baran, A. Balan, and L. K. Toppare, “Enhancing electrochromic and kinetic properties of poly(2,3-bis(4-tert-butylphenyl)-5,8-di(1H-pyrrol-2-yl) quinoxaline) by copolymerization,” ELECTROCHIMICA ACTA, pp. 2373–2376, 2010, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/36007.