Isolation of volatile oil from thyme (Thymbra spicata) by steam distillation

2003-08-01
The effects of steam flow rate (1.03 and 0.64 L/h), distillation time, and particle size (0.50, 1.00, 2.05 mm) of Thymbra spicata on essential oil yield and sequence of extraction of compounds were studied. A logarithmic model fitted well to experimental data. The composition of the essential oil obtained by steam distillation was investigated for whole leaves only since the grinding had an adverse effect on yield. The oil obtained was very rich with respect to its carvacrol content. For both steam flow rates, oxygenated monoterpenes were recovered the most rapidly. Using whole leaves (2.05 mm) and a higher steam flow rate (1.03 L/h) for 75 min of distillation was chosen as the optimum which gives the lowest amount of monoterpene hydrocarbons, the complete recovery of oxygenated compounds, and the highest yield in a shorter time. Yield was 1.57% at this optimum condition. The oil was composed of 53.1% oxygenated compounds, 25.7% monoterpene hydrocarbons, 4.4% sesquiterpenes, and 14.1% p-cymene.
NAHRUNG-FOOD

Suggestions

Extraction of some transition metals with N,N-dibutyl-N '-benzoylthiourea into molten paraffin at 65 degrees C
Merdivan, M; Gungor, A; Savasci, S; Aygün, Rüveyde Sezer (2000-10-02)
The solid-liquid extraction behaviour of some transition metals (Cu(II), Co(II), Ni(II), Cd(II) and Pb(II)) by the use of N,N-dibutyl-N'-benzoylthiourea as an extractant in paraffin (58-60 degrees C) has been investigated at 65.0 +/- 0.5 degrees C. The effect of equilibration time, pH of the aqueous phase, concentration of extractant and solid solvent used on the extraction efficiency of these metals have been discussed. The interferences of various ions are examined. The method has been applied to the dete...
Characterization of polylactide/poly(ethylene glycol) blends via direct pyrolysis mass spectrometry
Ozdemir, Esra; Tincer, Teoman; Hacaloğlu, Jale (2016-11-01)
In this study, melt blended poly(lactic acid) and poly(ethylene glycol), (PLA)/PEG samples involving 10, 15 and 20 wt% PEG were prepared and characterized by direct pyrolysis mass spectrometry technique in addition to classical techniques such differential scanning calorimetry, thermogravimetric analyses and mechanical tests. The incorporation of PEG resulted in consistent and significant decrease in the tensile strength and modulus, and reduction in endothermic melting peak of PLA due to the plasticizing e...
Characterization of the polymer of a dipyrrolyl monomer by pyrolysis mass spectrometry
Ertas, Merve; Hacaloğlu, Jale; Toppare, Levent Kamil (2004-08-01)
In this work, characterization of a homopolymer of succinic acid bis(4-pyrrol-1-ylphenyl) ester prepared by galvonastatic polymerization was carried out by direct pyrolysis mass spectrometry. Although decomposition of the monomer yielding mainly butadionic acid and pyrrole occurred under the galvonastatic polymerization conditions, growth of the polymer through the pyrrole moieties was also achieved, yielding a ladder-type polymer film. The polypyrrole chains contained both quinoid and aromatic units as in ...
Synthesis of new pyrazolium based tunable aryl alkyl ionic liquids and their use in removal of methylene blue from aqueous solution
Özdemir, Melek (2019-6-29)
In this study, two new pyrazolium based tunable aryl alkyl ionic liquids, 2-ethyl-1-(4-methylphenyl)-3,5- dimethylpyrazolium tetrafluoroborate (3a) and 1-(4-methylphenyl)-2-pentyl-3,5-dimethylpyrazolium tetrafluoroborate (3b), were synthesized via three-step reaction and characterized. The removal of methylene blue (MB) from aqueous solution has been investigated using the synthesized salts as an extractant and methylene chloride as a solvent. The obtained results show that MB was extracted from aqueous sol...
Synthesis and characterization of conducting copolymers of menthyl ester of 3-thiophene acetic acid with pyrrole
Kiralp, S; Alkan, S; Toppare, Levent Kamil; Cianga, I; Yagci, Y (2003-01-01)
A new thiophene derivative containing menthyl group (MM) was synthesized and polymerized via chemical and electrochemical (constant current) methods. Polymers obtained and MM itself were used to synthesize copolymers with pyrrole under conditions of constant potential electrolyses. Cyclic voltammetry (CV), thermal analysis (DSC, TGA) and scanning electron microscopy (SEM) analyses were performed for the characterization of samples.
Citation Formats
S. Hanci, S. Şahin, and L. Yılmaz, “Isolation of volatile oil from thyme (Thymbra spicata) by steam distillation,” NAHRUNG-FOOD, pp. 252–255, 2003, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/36527.