Synthesis and characterization of Ba/MCM-41

Date

2010-01-01

Author

Kaya, Emine
Oktar, Nuray
Karakaş, Gürkan
Murtezaoglu, Kirali

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Mesoporous Ba/MCM-41 type materials (Ba/MCM-41) with high Ba/Si molar ratios between 0.025 and 0.1 were synthesized by direct hydrothermal synthesis. The samples were characterized by XRD, nitrogen adsorption, TGA-DTA, FTIR, SEM-EDS, and TEM techniques. BET surface areas of samples with various Ba loadings were found between 722 and 931 m(2)/g with 28 A average pore size, which is consistent with the pore size of 30 A for pure MCM-41 samples synthesized by the same procedure. The crystal structures of synthesized MCM-41 and Ba/MCM-41 were confirmed by XRD analysis. Among the investigated Ba/MCM-41 samples, the formation of barium oxide and barium nitrate species besides silicates was also observed in the high angle region XRD patterns.

Subject Keywords

MCM-41, Hydrothermal synthesis

URI

https://hdl.handle.net/11511/37645

Journal

TURKISH JOURNAL OF CHEMISTRY

DOI

https://doi.org/10.3906/kim-1003-2

Collections

Department of Chemical Engineering, Article

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Citation Formats

E. Kaya, N. Oktar, G. Karakaş, and K. Murtezaoglu, “Synthesis and characterization of Ba/MCM-41,” TURKISH JOURNAL OF CHEMISTRY, pp. 935–943, 2010, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/37645.