Benzodithiophene and Benzotriazole Bearing Conjugated Polymers for Electrochromic and Organic Solar Cell Applications

Date

2017-01-01

Author

UNLU, Naime Akbasoglu
HACIOGLU, Serife O.
HIZALAN, Gonul
Yildiz, Dilber Esra
Toppare, Levent Kamil
Çırpan, Ali

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Herein, alternating donor-acceptor type benzodithiophene and benzotriazole bearing copolymers were synthesized and thieno[3,2-b] thiophene and furan units were incorporated as pi-bridges. The application of these polymers for electrochromic and photovoltaic studies were performed. Spectroelectrochemical studies illustrate that both polymers showed multichromic behavior due to tailoring of polaron bands in visible region. Photovoltaic properties of P2 were performed by conventional device structure. The best performance device based on P2: PC71BM (1: 3, w/w) exhibited the power conversion efficiency of 2.98%, with V-oc of 0.74 V, J(sc) of 6.31 mA/cm(2), and FF of 64%. The carrier mobility of the P2: PC71BM was calculated as 1.37 x 10- 3 cm(2)/V.s via space-charge-limited current method. (C) 2017 The Electrochemical Society.

Subject Keywords

Renewable Energy, Sustainability and the Environment, Electrochemistry, Materials Chemistry, Electronic, Optical and Magnetic Materials, Surfaces, Coatings and Films, Condensed Matter Physics

URI

https://hdl.handle.net/11511/37709

Journal

JOURNAL OF THE ELECTROCHEMICAL SOCIETY

DOI

https://doi.org/10.1149/2.0201707jes

Collections

Department of Chemistry, Article

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Citation Formats

N. A. UNLU, S. O. HACIOGLU, G. HIZALAN, D. E. Yildiz, L. K. Toppare, and A. Çırpan, “Benzodithiophene and Benzotriazole Bearing Conjugated Polymers for Electrochromic and Organic Solar Cell Applications,” JOURNAL OF THE ELECTROCHEMICAL SOCIETY, pp. 0–0, 2017, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/37709.