Effect of clay on crude oil combustion by thermal analysis techniques

Date

2006-05-01

Author

Kök, Mustafa Verşan

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This research was aimed to investigate the role of clay on the combustion and kinetic behavior of crude oils in limestone matrix. For this purpose, simultaneous TG (thermogravimetry) and DTA (differential thermal analysis) experiments were performed at three different heating rates as 10-15 and 20 degrees C min(-1), respectively. A uniform trend of decreasing activation energies was observed with the addition of clay. It was concluded that clays surface area affects the values of Arrhenius constant, while it is the catalytic properties of clay, which lower the activation energies of all the reactions, involved in the combustion process.

Subject Keywords

Physical and Theoretical Chemistry, Condensed Matter Physics, Clay, Crude oil, Differential thermal analysis, Heating rates, Reaction kinetics, Thermal analysis, Thermogravimetry

URI

https://hdl.handle.net/11511/37967

Journal

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY

DOI

https://doi.org/10.1007/s10973-005-7153-2

Collections

Department of Petroleum and Natural Gas Engineering, Article

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Influence of reservoir rock composition on the combustion kinetics of crude oil Kök, Mustafa Verşan (Springer Science and Business Media LLC, 2009-08-01) In this research, the effect of different lithology (limestone and sandstone) on the combustion of light crude oils was investigated using thermal analysis techniques. Three distinct reaction regions were identified in all of the crude oil+limestone and sandstone mixtures, known as low temperature oxidation (LTO), fuel deposition (FD) and high temperature oxidation (HTO), respectively. Kinetic analysis of the crude oil+limestone and sandstone mixtures was performed using Coats and Redfern method and the res...
Effect of metal oxide on light oil combustion - TA and kinetic analysis Kök, Mustafa Verşan (Springer Science and Business Media LLC, 2003-01-01) Simultaneous thermogravimetry (TG) and differential thermal analysis (DTA) were applied to light crude oil combustion in the presence and absence of metal oxide. In crude oil-limestone mixture, three main transitional stages are detected. These are distillation, low-temperature oxidation (LTO) and high temperature oxidation (HTO) regions respectively. In the case of experiments with Fe(III)chloride at different amounts, the shape of TG-DTA curve is changed considerably. Kinetic parameters of the samples are...
Effect of pressure and particle size on the thermal cracking of light crude oils in sandstone matrix Kök, Mustafa Verşan (Springer Science and Business Media LLC, 2009-4-27) This research is focused on the effects of pressure (100-300 Pa) and matrix and on light crude oil combustion in sandstone matrix using pressurized differential scanning calorimetry (PDSC). Light crude oils and sandstone mixtures were prepared to give a composition of 15 mass% crude oil in sandstone matrix. A total of forty-eight PDSC experiments were performed. Roger and Morris kinetic model was used to analyse the data obtained from PDSC experiments and the results are discussed.
Light crude oil combustion in the presence of limestone matrix Kök, Mustafa Verşan; Keskin, C; Madarasz, J; Bagci, S (Springer Science and Business Media LLC, 2004-01-01) In this study the combustion characteristics of crude oils (Karakus and Beykan) in the presence of a limestone matrix were determined using the thermogravimetry (TG/DTG). Experiments were performed at a heating rate of 10degreesC min(-1), whereas the air flow rate was kept constant at 10 L h(-1) in the temperature range of 20-900degreesC. In combustion with air, three distinct reaction regions were identified in all crude oil/limestone mixtures studied known as low temperature oxidation (LTO), fuel depositi...

Citation Formats

M. V. Kök, “Effect of clay on crude oil combustion by thermal analysis techniques,” JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, pp. 361–366, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/37967.