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Synthesis and Electrochemical Polymerization of Dithienosilole-Based Monomers Bearing Different Donor Units
Date
2016-01-01
Author
Eken, S.
Ergun, E. G. Cansu
Önal, Ahmet Muhtar
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Three new donor-acceptor-donor (DAD) type monomers containing five membered heteroaromatic rings as the donor units and the silicon-bridged bithiophene as the acceptor unit were synthesized via Stille cross-coupling reaction. The monomers, 2,6-di(furan-2-yl)-4,4-dioctyl-4H-silolo[3,2-b:4,5-b'] dithiophene (FSiF), 4,4-dioctyl-2,6-di(thiophen-2-yl)-4H-silolo[3,2-b:4,5-b']dithiophene (TSiT) and 4,4-dioctyl-2,6-di(selenophen-2-yl)-4H-silolo[3,2-b:4,5-b'] dithiophene (SeSiSe) were polymerized electrochemically via potential cycling in acetonitrile-tetrabutylammonium perchlorate electrolytic medium. Optical and electrochemical properties of the monomers and their corresponding polymers were investigated and it was found that oxidation potentials of the monomers and optical properties of both monomers and their polymers showed slight variations depending on the heteroatom present in the donor unit. (C) 2016 The Electrochemical Society.
Subject Keywords
Renewable Energy, Sustainability and the Environment
,
Electrochemistry
,
Materials Chemistry
,
Electronic, Optical and Magnetic Materials
,
Surfaces, Coatings and Films
,
Condensed Matter Physics
URI
https://hdl.handle.net/11511/38142
Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
DOI
https://doi.org/10.1149/2.0521606jes
Collections
Department of Chemistry, Article
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S. Eken, E. G. C. Ergun, and A. M. Önal, “Synthesis and Electrochemical Polymerization of Dithienosilole-Based Monomers Bearing Different Donor Units,”
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
, pp. 0–0, 2016, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/38142.