Conducting polymer composites of polypyrrole and a poly(arylene ether ketone)

Date

1998-01-01

Author

Selampinar, F
Akbulut, Ural
Toppare, Levent Kamil

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

178
views

0
downloads

Electrically conducting composites of polypyrrole and a poly(arylene ether ketone) were synthesized by electroinitiated polymerization of pyrrole on a poly(arylene ether ketone)-coated platinum electrode. The electrolysis medium was water and p-toluene sulfonic acid. The conductivities of the composites were in the range 1-10 S/cm. The composites were characterized by scanning electron microscopy, Fourier transform infrared, and thermal analyses. The composites were found to be composed of bilayers which can be peeled into two free-standing polymer films. The solution side of the polypyrrole layer of the alloy film contains globular structures, whereas the other side is smoother.

Subject Keywords

Materials Chemistry, Materials Science (miscellaneous), General Chemical Engineering, Polymers and Plastics

URI

https://hdl.handle.net/11511/38643

Journal

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING

DOI

https://doi.org/10.1080/03602559808006928

Collections

Department of Chemistry, Article

Suggestions

OpenMETU
Core

Synthesis and mesophase properties of block and random co-polymers of electroactive and liquid crystalline monomers Yilmaz, F; Kasapoglu, F; Hepuzer, Y; Yagci, Y; Toppare, Levent Kamil; Fernandes, EG; Galli, G (Informa UK Limited, 2005-01-01) Homo-polymers and random co-polymers of electroactive and liquid crystalline monomers, namely 3-thienylmethyl methacrylate (MTM) and 6-(4-cyanobiphenyl-4'-oxy)hexyl acrylate (LC6), were prepared by conventional free radical polymerization. Block co-polymers of MTM and LC6 were also synthesized by using the 1,1-diphenylethene (DPE) method. The obtained random and block co-polymers exhibited liquid crystal behavior depending on the content of the LC6 units. It was found that microphase separation of the polym...
Polymerization and characterization of trihalophenolato cerium(IV) complexes in the solid state and in the melt Senturk, O; Kisakurek, D (Informa UK Limited, 2003-01-01) The synthesis of trihalophenolate cerium (IV) complexes from an aqueous solution and their characterizations by means of FTIR, DSC, elemental analyses, mass spectroscopy, and magnetic susceptibility measurements are described. The thermal polymerizations of these complexes were carried out in the solid state and in the melt. Structural analyses of polymers were performed by H-1-NMR, C-13-NMR, and FTIR spectroscopic analyses; T-g by differential scanning calorimetry; as well as the molecular weights by visco...
Conducting copolymers of thiophene functionalized polystyrenes with thiophene Sahin, E; Camurlu, P; Toppare, Levent Kamil; Mercore, VM; Cianga, I; Yagci, Y (Elsevier BV, 2005-06-01) Thiophene capped polystyrenes (TCP1, TCP2) were synthesized by atom transfer radical polymerization of styrene followed by Suzuki condensation with 2-thiophene boronic acid. Electrically conducting graft polymers of TCP1 and TCP2 with thiophene were achieved by electrochemical methods. Characterization of the graft polymers were performed by cyclic voltammetry (CV), Fourier transform infrared spectroscopy, differential scanning calorimetry, scanning electron microscopy analyses. Electrochromic properties of...
Synthesis and Characterization of Conducting Copolymers of Bisphenol A-Diglycidyl Ether with Thiophene Side-Groups and Pyrrole Sahmetlioglu, Ertugrul; Varol, Ramazan; Toppare, Levent Kamil; Yuruk, Huseyin (Informa UK Limited, 2009-01-01) Copolymers of bisphenol A-diglycidyl ether with thiophene side-groups and pyrrole were synthesized by electrochemical polymerization. Bisphenol A-diglycidyl ether with thiophene side-groups (DGEBATh) was obtained from the reaction between bisphenol A-diglycidyl ether (DGEBA) and thiophene-3-acetic acid. The syntheses of copolymers of DGEBATh and pyrrole were achieved electrochemically using three different supporting electrolytes, p-toluene sulfonic acid (PTSA), sodium dodecyl sulfate (SDS) and tetrabutylam...
Conducting copolymers of thiophene-functionalized polystyrene Papila, O; Toppare, Levent Kamil; Yagci, Y; Cianga, L (Informa UK Limited, 2004-01-01) The syntheses of conducting copolymers of thiophene-functionalized polystyrene and pyrrole (PS/PPy) were achieved using p-toluene sulfonic acid (PTSA) as the supporting electrolyte via constant potential electrolysis technique. Characterization of the samples was performed by a combination of techniques: cyclic voliammetry (CV), thermogravimetric analysis (TGA), differential scanning colorimetry (DSC), scanning electron microscopy (SEM), NMR, and FT-IR analyses. The conductivities were measured by the four-...

Citation Formats

F. Selampinar, U. Akbulut, and L. K. Toppare, “Conducting polymer composites of polypyrrole and a poly(arylene ether ketone),” POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, pp. 295–302, 1998, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/38643.