ASYMMETRIC ENE REACTIONS OF 2-METHYLPROPENE WITH CHLOROALDEHYDES IN THE PRESENCE OF BORONTRIFLUORIDE-L-MENTHYLETHYL ETHERATE

1994-01-01
AKHMEDOV, IM
Tanyeli, Cihangir
AKHMEDOV, MA
MOHAMMADI, M
DEMIR, AS
The asymmetric ene reactions of prochiral chloroaldehydes, chloral and 2,3-dichlorobutanal with 2-methylpropanal in the presence of BF3 l-menthylethyl etherate gave optically active homoallylic alcohols in 16-22% ee. The dechlorination of the chloro alcohols lead to the unsaturated derivatives of alcohols.

Citation Formats
I. AKHMEDOV, C. Tanyeli, M. AKHMEDOV, M. MOHAMMADI, and A. DEMIR, “ASYMMETRIC ENE REACTIONS OF 2-METHYLPROPENE WITH CHLOROALDEHYDES IN THE PRESENCE OF BORONTRIFLUORIDE-L-MENTHYLETHYL ETHERATE,” SYNTHETIC COMMUNICATIONS, vol. 24, no. 2, pp. 137–143, 1994, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/38796.