Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
Transport of metals leaching from land-disposed oil field wastes
Date
1998-12-01
Author
Ünlü, Kahraman
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
232
views
0
downloads
Cite This
The potential for groundwater contamination by metals leaching from land-disposed oil field exploration and production (E&P) wastes is an environmental concern. In this study a geochemical transport model is adopted to consider multispecies metal migration. Objectives are to characterize the chemical composition of E&P wastes, to evaluate the mobility and pollution potential of metals in E&P wastes and to investigate the utility of simplified modelling approaches. A chemical transport model coupling a hydrologic submodel is used for the analysis. The hydrologic transport submodel considers one-dimensional advective-dispersive transport: of components in the aqueous phase under steady unsaturated flow conditions. The geochemical submodel considers speciation, precipitation-dissolution and ion exchange reactions assuming local equilibrium conditions prevail. Simulations are performed to evaluate the movement of metals through the unsaturated zone for the base case corresponding to a typical waste pit. Sensitivity analyses are performed for selected input parameters that are expected to have significant effect on metal transport. Breakthrough curves (BTCs) are obtained for metal species As, Ba, Cd, Cr, Cu, Pb and Zn at the water table. Inspection of BTCs reveals multiple peaks and complex interrelationships among model parameters which cannot be reproduced using single species transport models with linear reaction terms. Precipitation plays a significant role in attenuation of metal concentrations in E&P wastes. Calculated vadose zone attenuation ratios indexing the pollution potential of various metals span a wide range of values due to the differences in reactivity of metals. Results for the relative vadose zone concentration with respect to maximum contaminant levels in drinking water suggest that, in general, chloride is likely to to be more critical than trace metals in controlling the groundwater quality. Cadmium and copper are the next most likely to lead to non compliance. Under conditions where Cr(III) is the dominant species in waste, chromium attenuation is greatly increased due to precipitation.
Subject Keywords
Environmental Engineering
,
Pollution
URI
https://hdl.handle.net/11511/38944
Journal
WASTE MANAGEMENT & RESEARCH
DOI
https://doi.org/10.1177/0734242x9801600605
Collections
Department of Environmental Engineering, Article
Suggestions
OpenMETU
Core
Modeling natural attenuation of petroleum hydrocarbons (btex) in heterogeneous aquifers
Uçankuş, Tuğba; Ünlü, Kahraman; Department of Environmental Engineering (2005)
Natural Attenuation can be an effective cleanup option for remediation of Groundwater contamination by BTEX. One of the important aspects of the methodology that has been recognized recently is that mass removal rates, the most important parameters used to determine effectiveness of the methodology, is controlled by groundwater flow regime, which to a large extent controlled by aquifer heterogeneity. Considering this recognition, the primary objective of this research is to quantitatively describe the relat...
Treatability of chromite ore processing waste by leaching
Ünlü, Kahraman (SAGE Publications, 2001-06-01)
Developing treatment and disposal strategies and health-based clean-up standards for chromium containing wastes continues to be an important environmental regulatory issue because of the opposing solubility and toxicity characteristics of chromium species under diverse environmental conditions. In this study, leaching characteristics of total Cr and Cr(VI) were investigated using laboratory column studies. The data obtained from the experimental studies were analysed to assess the treatability of chromite o...
Identification of waste management strategies and waste generation factors for thermal power plant sector wastes in Turkey
Demir, Cansu; Yetiş, Ülkü; Ünlü, Kahraman (SAGE Publications, 2019-03-01)
Thermal power plants are of great environmental importance in terms of the huge amounts of wastes that they produce. Although there are process-wise differences among these energy production systems, they all depend on the logic of burning out a fuel and obtaining thermal energy to rotate the turbines. Depending on the process modification and the type of fuel burned, the wastes produced in each step of the overall process may change. In this study, the most expected process and non-process wastes stemming ...
The effects of aquifer heterogeneity on the natural attenuation rates of chlorinated solvents
Önkal, Başak; Ünlü, Kahraman; Department of Environmental Engineering (2005)
Monitored natural attenuation has been particularly used at sites where petroleum hydrocarbons and chlorinated solvents have contaminated soil and groundwater. One of the important aspects of the methodology that has been recognized recently is that the mass removal rates, the most important parameter to determine effectiveness of the methodology, is controlled by the groundwater flow regime and the aquifer heterogeneity. Considering this recognition, the primary objective of this study is to quantitatively...
Assessment of PCB contamination, the potential for in situ microbial dechlorination and natural attenuation in an urban watershed at the East Coast of the United States
Kaya, Devrim; Sowers, Kevin R.; Demirtepe, Hale; Stiell, Brian; Baker, Joel E.; İmamoğlu, İpek; Kjellerup, Birthe (Elsevier BV, 2019-09-15)
Sediment contamination is a major environmental issue in many urban watersheds and coastal areas due to the potential toxic effects of contaminants on biota and human health. Characterizing and delineating areas of sediment contamination and toxicity are important goals of coastal resource management in terms of ecological and economical perspectives. Core and surficial sediment samples were collected from an industrialized urban watershed at the East Coast of the United Stated and analyzed to evaluate the ...
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
K. Ünlü, “Transport of metals leaching from land-disposed oil field wastes,”
WASTE MANAGEMENT & RESEARCH
, pp. 541–554, 1998, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/38944.