Synthesis and photophysical property of well-defined donor-acceptor diblock copolymer based on regioregular poly(3-hexylthiophene) and fullerene

Date

2009-03-04

Author

LEE, Jea Uk
Çırpan, Ali
EMRICK, Todd
RUSSELL, Thomas P.
JO, Won Ho

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A new, well-defined diblock copolymer (P3HT-b-C60) based on regioregular poly(3-hexylthiophene) (P3HT) and fullerene was synthesized. First, regioregular P3HT was synthesized through Grignard metathesis polymerization, and then methyl methacrylate (MMA) and 2-hydroxyethyl methacrylate (HEMA) were copolymerized by using an end-functionalized P3HT as a macroinitiator for the atom transfer radical polymerization to yield a diblock copolymer (P3HT-b-P(MMA-r-HEMA)). A fullerene derivative functionalized with carboxylic acid, [6,6]-phenyl-C61-butyric acid (PCBA), was then chemically linked to the HEMA unit in the second block (P(MMA-r-HEMA)) to produce a diblock copolymer with the second block containing fullerenes. Annealing thin films of the copolymer revealed nanometer-scale phase separation, a more suitable morphology for enabling excitons generated in the P3HT domain to more efficiently reach the donor–acceptor interface, relative to simple blends of P3HT and C60. As a result, photoluminescence of the P3HT-b-C60diblock copolymer in the films showed a complete quenching of photoluminescence of P3HT, which is indicative of charge transfer between P3HT and fullerene.

Subject Keywords

Materials Chemistry, General Chemistry

URI

https://hdl.handle.net/11511/40262

Journal

Journal of Materials Chemistry

DOI

https://doi.org/10.1039/b813368a

Collections

Department of Chemistry, Article

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Citation Formats

J. U. LEE, A. Çırpan, T. EMRICK, T. P. RUSSELL, and W. H. JO, “Synthesis and photophysical property of well-defined donor-acceptor diblock copolymer based on regioregular poly(3-hexylthiophene) and fullerene,” Journal of Materials Chemistry, pp. 1483–1489, 2009, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/40262.