Aqueous-phase hydrodechlorination of trichloroethylene over Pd-based swellable organically-modified silica (SOMS): Catalyst deactivation due to chloride anions

Date

2018-12-30

Author

Çelik, Gökhan
Gunduz, Seval
Miller, Jeffrey T.
Edmiston, Paul L.
Ozkan, Umit S.

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Swellable-organically modified silica (SOMS) has been demonstrated to be an efficient catalyst scaffold for catalytic treatment of water contaminated with trichloroethylene (TCE). In this study, deactivation characteristics of Pd-incorporated SOMS for aqueous-phase hydrodechlorination (HDC) of TCE were investigated. Pd/SOMS catalysts were exposed to highly-concentrated chloride solutions (up to 1 M NaCl or 0.01 M HCl) to examine the deactivation resistant behavior of Pd/SOMS. The commonly used HDC catalyst Pd/Al2O3 was also studied for comparison purposes. Pd/SOMS and Pd/Al2O3 in their pristine and treated states were tested for aqueous-phase HDC of TCE and characterized by several techniques including N2 physisorption, inductively coupled plasma optical emission spectroscopy (ICP-OES), X-ray photoelectron spectroscopy, extended X-ray absorption fine structure spectroscopy (EXAFS), and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) of adsorbed CO. The aqueous-phase treatments had a pronounced adverse effect on the textural properties of Pd/Al2O3, although the effect was independent of the type of the chloride precursor, NaCl or HCl. Treating Pd/Al2O3 with chloride-containing solutions lowered the catalytic activity due to formation of Pd-Cl complexes and active metal leaching. The leached Pd obtained from the treatment solution was shown to be inactive for aqueous-phase HDC of TCE. While Pd/Al2O3 underwent severe deactivation due to the chloride treatments, Pd/SOMS exhibited resistance to chloride deactivation and metal leaching. The chloride treatments did not impact the textural properties of Pd/SOMS. The achieved deactivation resistance was attributed to the novel characteristics of the SOMS support.

Subject Keywords

Process Chemistry and Technology, General Environmental Science, Catalysis

URI

https://hdl.handle.net/11511/40814

Journal

Applied Catalysis B: Environmental

DOI

https://doi.org/10.1016/j.apcatb.2018.08.065

Collections

Department of Chemical Engineering, Article

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Citation Formats

G. Çelik, S. Gunduz, J. T. Miller, P. L. Edmiston, and U. S. Ozkan, “Aqueous-phase hydrodechlorination of trichloroethylene over Pd-based swellable organically-modified silica (SOMS): Catalyst deactivation due to chloride anions,” Applied Catalysis B: Environmental, pp. 654–664, 2018, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/40814.