An integrated process for partial oxidation of alkanes

Zhou, XP
Yılmaz, Ayşen
Yilmaz, GA
Lorkovic, YM
Laverman, LE
Weiss, M
Sherman, JH
McFarland, EW
Stucky, GD
Ford, PC
The partial oxidation of alkanes via bromination followed by the reaction with solid metal oxide mixtures (MO) is shown to give an array of products that can be tuned by varying the MO and the reaction conditions.


A soluble conducting polymer of 2,5-di(thiophen-2-yl)-1-p-tolyl-1H-pyrrole and its electrochromic device
YİGİTSOY, Basak; VARİS, Serhat; Tanyeli, Cihangir; Akhmedov, Idris M.; Toppare, Levent Kamil (Elsevier BV, 2007-02-26)
A monomer 2,5-di(thiophen-2-yl)-1-p-tolyl-1H-pyrrole was synthesized via reaction of 1,4-di(2-thienyl)-1,4-butanedione and p-toluidine in the presence of catalytical amount of p-toluenesulfonic acid. Chemical polymerization of the monomer yielded a soluble polymer. The average molecular weight was determined by gel permeation chromatography as number average molecular weight (Mn) 2.5 x 10(3) g/mol. The monomer was also electrochemically polymerized in the presence of LiClO4, NaClO4 (1:1) as the supporting e...
Direct enantioselective aldol reactions catalyzed by a proline-thiourea host-guest complex
Reis, Oemer; Eymur, Serkan; Reis, Barbaros; Demir, Ayhan Sıtkı (Royal Society of Chemistry (RSC), 2009-01-01)
Proline-thiourea host-guest complex-catalyzed direct enantioselective aldol reactions have been developed, in which the catalytic activities were evaluated in the direct asymmetric aldol reactions of various aromatic aldehydes and cyclohexanone.
One-component, switchable ionic liquids derived from siloxylated amines
Blasucci, Vittoria; Dilek Hacıhabiboğlu, Çerağ; Huttenhower, Hillary; John, Ejae; Llopis-Mestre, Veronica; Pollet, Pamela; Eckert, Charles A; Liotta, Charles (Royal Society of Chemistry (RSC), 2009-01-01)
A new class of one-component, thermally reversible, neutral to ionic liquid solvents derived from siloxylated amines is presented and characterized.
Synthesis and characterization of conducting copolymers of succinic acid bis-(4-pyrrol-1-yl-phenyl) ester and their electrochromic properties
Ertas, M; Çırpan, Ali; Toppare, Levent Kamil (Elsevier BV, 2004-05-07)
A new dipyrrolyl monomer was synthesized via the reaction between 4-pyrrol-1-yl phenol and butanedioyl dichloride. Electrochemical behavior of this monomer, succinic acid bis-(4-pyrrol-1-yl-phenyl) ester (SM) was studied. Homopolymerization was achieved by chemical and constant Current electrolysis methods. Copolymerization of SM with thiophene was performed by constant potential electrolysis in acetonitrile (AN)-tetrabutylammonium tetrafluoroborate (TBAFB) and dichloromethane (DCM)-TBAFB, solvent-electroly...
A neutral state yellow to navy polymer electrochrome with pyrene scaffold
Icli-Ozkut, Merve; Oztas, Zahide; Algi, Fatih; CİHANER, ATİLLA (Elsevier BV, 2011-09-01)
A new pyrene based soluble polymer, namely poly(3,3-didecyl-6-(1-(3,3-didecyl-3,4-dihydro-2H-thieno[3,4-b][1,4] dioxepin-6-yl) pyren-6-yl)-3,4-dihydro-2H-thieno[3,4-b][1,4] dioxepine), P5, which is synthesized by both chemical and electrochemical methods, is highlighted. The polymer shows both electrochromic and fluorescent properties (the emission of yellow (545 nm) and yellowish green light (524 nm) in solid state and in THF solution, respectively). It is noteworthy that P5 has a specific optical band gap...
Citation Formats
X. Zhou et al., “An integrated process for partial oxidation of alkanes,” CHEMICAL COMMUNICATIONS, pp. 2294–2295, 2003, Accessed: 00, 2020. [Online]. Available: