Poly(o-aminophenol) prepared by Cu(II) catalyzed air oxidation and its use as a bio-sensing architecture

Date

2017-07-14

Author

Bicak, Tugrul Cem
Soylemez, Saniye
Buber, Ece
Toppare, Levent Kamil
Yağcı, Yusuf

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A novel procedure for the preparation of organosoluble polyo-aminophenol) is described. The method pertains to the reduction of CuBr2 with o-amino phenol OAP) at room temperature. The air oxidation of the CuI) species to Cu(II) facilitated the formation of polyo-aminophenol) POAP) in repeated cycles. The obtained polymer, soluble in common organic solvents such as dimethylformamide, acetone, and chloroform, was characterized by spectral analyses. It was found that both quinoid and benzoid structures were present in the polymer chain. Polyo-aminophenol) architecture was then applied as an immobilization matrix to obtain a long-lived and fast response bio-sensing system. Glucose oxidase GOx) was utilized as a model enzyme for the detection of glucose in beverages. After the optimization studies, the surface characterization of POAP/GOx was performed by scanning electron microscopy SEM) measurements. Under the optimized conditions, the biosensor exhibited a rapid response 2 s), a low detection limit 0.02 mM), and high sensitivity 79.80 mu A mM(-1) cm(-2)). The K-M(app) value was determined as 0.16 mM. Furthermore, there was no considerable activity loss for 15 days for the POAP/GOx biofilm indicating excellent recovery as tested with real samples.

Subject Keywords

Immobilization, Polyaniline, gold electrode, Thermal-stability, Platinum-electrode, Prussian blue, Conducting polymer, Dlucose biosensor, o-aminophenol film, Elassy-carbon electrode

URI

https://hdl.handle.net/11511/42574

Journal

POLYMER CHEMISTRY

DOI

https://doi.org/10.1039/c7py00807d

Collections

Department of Chemistry, Article

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Citation Formats

T. C. Bicak, S. Soylemez, E. Buber, L. K. Toppare, and Y. Yağcı, “Poly(o-aminophenol) prepared by Cu(II) catalyzed air oxidation and its use as a bio-sensing architecture,” POLYMER CHEMISTRY, pp. 3881–3888, 2017, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/42574.