OXIDATION OF ARYL ALKYL KETONES TO ALPHA-ACYLOXY, ALPHA-(CAMPHORSULFONYLOXY), OR ALPHA-HYDROXY DERIVATIVES USING MANGANESE(III) ACETATE IN COMBINATION WITH CARBOXYLIC-ACIDS OR (1S)-(+)-10-CAMPHORSULFONIC ACID

Date

1990-01-01

Author

DEMIR, AS
CAMKERTEN, N
AKGUN, H
Tanyeli, Cihangir
MAHASNEH, AS
WATT, DS

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The α-oxidation of aryl alkyl ketones using manganese(III) acetate in the presence of various carboxylic acids and (1S)-(+)-10-camphorsulfonic acid provided a convenient synthesis of α-acyloxy, α-(10-camphorsulfonyloxy), and α-hydroxy derivatives in good yield.

Subject Keywords

Organic Chemistry

URI

https://hdl.handle.net/11511/42577

Collections

Department of Chemistry, Article