OXIDATION OF ARYL ALKYL KETONES TO ALPHA-ACYLOXY, ALPHA-(CAMPHORSULFONYLOXY), OR ALPHA-HYDROXY DERIVATIVES USING MANGANESE(III) ACETATE IN COMBINATION WITH CARBOXYLIC-ACIDS OR (1S)-(+)-10-CAMPHORSULFONIC ACID

1990-01-01
DEMIR, AS
CAMKERTEN, N
AKGUN, H
Tanyeli, Cihangir
MAHASNEH, AS
WATT, DS
The α-oxidation of aryl alkyl ketones using manganese(III) acetate in the presence of various carboxylic acids and (1S)-(+)-10-camphorsulfonic acid provided a convenient synthesis of α-acyloxy, α-(10-camphorsulfonyloxy), and α-hydroxy derivatives in good yield.

Citation Formats
A. DEMIR, N. CAMKERTEN, H. AKGUN, C. Tanyeli, A. MAHASNEH, and D. WATT, “OXIDATION OF ARYL ALKYL KETONES TO ALPHA-ACYLOXY, ALPHA-(CAMPHORSULFONYLOXY), OR ALPHA-HYDROXY DERIVATIVES USING MANGANESE(III) ACETATE IN COMBINATION WITH CARBOXYLIC-ACIDS OR (1S)-(+)-10-CAMPHORSULFONIC ACID,” SYNTHETIC COMMUNICATIONS, vol. 20, no. 15, pp. 2279–2289, 1990, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/42577.