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Temperature dependence of the Raman bandwidths and intensities of a lattice mode near the tricritical and second order phase transitions in NH4Cl
Date
2006-01-11
Author
Karacali, H
Yurtseven, Hasan Hamit
Metadata
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We calculate here the temperature dependence of the damping constant using the expressions derived from the Matsushita's theory and the temperature dependence of the order parameter from the molecular field theory for the tricritical (1.5 kbar) and second order (2.8 kbar) phase transitions in NH4Cl. Our calculations are performed for the nu(5) (174 cm(-1)) Raman mode of NH4Cl for the pressures studied. Predictions for the damping constant are in good agreement with our observed Raman bandwidths of this lattice mode for both pressures. The Raman intensities calculated from the molecular field theory by means of the order parameter are also in good agreement with our observed Raman intensities of the nu(5) (174 cm(-1)) mode for both tricritical (1.5 kbar) and second order (2.8 kbar) phase transitions in NH4Cl. In this study our observed Raman intensities of this lattice mode are analysed using a power-law formula with the critical exponent beta for the order parameter at those two pressures considered in NH4Cl. From our analysis, the value of beta=0.5 is obtained as the mean. eld value.
Subject Keywords
Order-Disorder Transition
,
Neutron-Diffraction
,
Optical Phonons
,
Scattering
,
Diagram
,
Frequency
,
Crystals
,
Lambda
,
Spectra
,
NH4BR
URI
https://hdl.handle.net/11511/42684
Journal
PHILOSOPHICAL MAGAZINE
DOI
https://doi.org/10.1080/1478630500375167
Collections
Department of Physics, Article
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Temperature and Pressure Effect on the Raman Frequencies Calculated from the Crystal Volume in the gamma-Phase of Solid Nitrogen
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The temperature and pressure dependences of the Raman frequencies of the lattice modes (E-g and B-1g modes) and of an internal mode (2331 cm(-1)) are predicted using the observed molar volume data from the literature in the gamma-phase of solid N-2. This calculation is carried out by means of the mode Gruneisen parameter of each Raman mode in the gamma-phase of solid nitrogen. Our results show that the predicted Raman frequencies of the E-g mode increase as the pressure increases. The Raman frequencies of t...
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H. Karacali and H. H. Yurtseven, “Temperature dependence of the Raman bandwidths and intensities of a lattice mode near the tricritical and second order phase transitions in NH4Cl,”
PHILOSOPHICAL MAGAZINE
, pp. 189–203, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/42684.