A new p- and n-dopable selenophene derivative and its electrochromic properties

Date

2009-02-01

Author

Cetin, Guelben Ardahan
Balan, Abidin
Durmus, Asuman
Günbaş, Emrullah Görkem
Toppare, Levent Kamil

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A novel electrically conducting polymer, poly(2-dodecyl-4,7-di(selenophen-2-yl)benzotriazole) (PSBT), containing selenophene as the strong donor and benzotriazole as the strong acceptor groups was synthesized by electrochemical polymerization. Homopolymerization and copolymerization (in the presence of 3,4-ethylenedioxythiophene (EDOT)) were achieved in acetonitrile/dichloromethane(95/5 v/v) with 0.1 M tetrabutylammonium hexafluorophosphate (TBAPF(6)). The electrochemical and optical properties of homopolymer and copolymer were investigated by cyclic voltammetry, UV-Vis, near IR Spectroscopy. Cyclic voltammetry and spectroelectrochemistry studies demonstrated that homopolymer can be reversibly reduced and oxidized (both n- and p-doped) between -1.9V and +1.4V. at a scan rate of 100 mV/s. The homopolymer revealed a transmissive light blue color in the oxidized state, and a red-purple color in the neutral state. A transmissive light blue color was also observed in the reduced state. Homopolymer films could be fully switched between their reduced and oxidized forms in 2.4 s and 0.4 s with a percent transmittance of 32% and 56% at 511 and 1200 nm, respectively. Poly(SBT) exhibits a lambda(max) value of 511 nm and a band gap of 1.67 eV which is quite low among the selenophene-containing polymers reported so far except for poly(1,2-bis(2-seleninyl)ethane).

Subject Keywords

Electrical and Electronic Engineering, Materials Chemistry, Electronic, Optical and Magnetic Materials, General Chemistry, Condensed Matter Physics, Biomaterials

URI

https://hdl.handle.net/11511/43335

Journal

ORGANIC ELECTRONICS

DOI

https://doi.org/10.1016/j.orgel.2008.09.004

Collections

Department of Chemistry, Article

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Citation Formats

G. A. Cetin, A. Balan, A. Durmus, E. G. Günbaş, and L. K. Toppare, “A new p- and n-dopable selenophene derivative and its electrochromic properties,” ORGANIC ELECTRONICS, pp. 34–41, 2009, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/43335.