Synthesis of ferrocenyl quinones

Date

2003-03-03

Author

Zora, Metin
Acikalin, S

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A squarate-based synthesis of ferrocenyl quinones is described. Thermolysis of ferrocenyl-substituted cyclobutenones, prepared from ferrocenyl cyclobutenediones and alkenyllithiums, affords hydroquinones, which furnish, upon oxidation, ferrocenyl quinones. Ferrocenyl cyclobutenediones have been prepared from known cyclo butenediones by nucleophilic addition of ferrocenyllithium followed by hydrolysis, Pd/Cu-cocatalyzed cross-coupling with (tri-n-butylstannyl)ferrocene or Friedel-Crafts alkylation with ferrocene.

Subject Keywords

Organic Chemistry, Biochemistry, Drug Discovery

URI

https://hdl.handle.net/11511/46299

Journal

TETRAHEDRON LETTERS

DOI

https://doi.org/10.1016/s0040-4039(03)00099-6

Collections

Department of Chemistry, Article

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Citation Formats

M. Zora and S. Acikalin, “Synthesis of ferrocenyl quinones,” TETRAHEDRON LETTERS, pp. 2237–2241, 2003, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/46299.