Spectroelectrochemical investigation of the anodic oxidation of dibenzo-18-crown-6

Date

2004-10-01

Author

Cihaner, A
Önal, Ahmet Muhtar

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Poly(dibenzo-18-crown-6) (poly-DB18C6) was synthesized by electrochemical oxidation of dibenzo-18-crown-6 (DB18C6) using a mixture of acetonitrile and dichloromethane as the solvent and tetrabutylammonium tetrafluoroborate (TBABF(4)) or tetrabutylammonium hexafluorophosphate (TBAPF(6)) as supporting electrolyte. The anodic polymerization of DB18C6 was investigated using in situ ESR and in situ UV-Vis spectroscopic techniques. Spectroelectrochemical (SPEL), properties and thermal analysis of the resulting polymers have been investigated using UV-Vis spectroscopy, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).

Subject Keywords

Analytical Chemistry, Electrochemistry, General Chemical Engineering

URI

https://hdl.handle.net/11511/46475

Journal

JOURNAL OF ELECTROANALYTICAL CHEMISTRY

DOI

https://doi.org/10.1016/j.jelechem.2004.05.005

Collections

Department of Chemistry, Article

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Citation Formats

A. Cihaner and A. M. Önal, “Spectroelectrochemical investigation of the anodic oxidation of dibenzo-18-crown-6,” JOURNAL OF ELECTROANALYTICAL CHEMISTRY, pp. 159–167, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/46475.