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Spectroelectrochemical investigation of the anodic oxidation of dibenzo-18-crown-6
Date
2004-10-01
Author
Cihaner, A
Önal, Ahmet Muhtar
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Poly(dibenzo-18-crown-6) (poly-DB18C6) was synthesized by electrochemical oxidation of dibenzo-18-crown-6 (DB18C6) using a mixture of acetonitrile and dichloromethane as the solvent and tetrabutylammonium tetrafluoroborate (TBABF(4)) or tetrabutylammonium hexafluorophosphate (TBAPF(6)) as supporting electrolyte. The anodic polymerization of DB18C6 was investigated using in situ ESR and in situ UV-Vis spectroscopic techniques. Spectroelectrochemical (SPEL), properties and thermal analysis of the resulting polymers have been investigated using UV-Vis spectroscopy, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).
Subject Keywords
Analytical Chemistry
,
Electrochemistry
,
General Chemical Engineering
URI
https://hdl.handle.net/11511/46475
Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
DOI
https://doi.org/10.1016/j.jelechem.2004.05.005
Collections
Department of Chemistry, Article
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A. Cihaner and A. M. Önal, “Spectroelectrochemical investigation of the anodic oxidation of dibenzo-18-crown-6,”
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
, pp. 159–167, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/46475.