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Calculation of the frequency shifts and damping constant for the Raman modes (A(1g), B-1) near the tetragonal-cubic transition in SrTiO3
Date
2017-01-01
Author
KİRACI, ALİ
Yurtseven, Hasan Hamit
Metadata
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Raman shifts of the soft mode A(1g) and the B-1 mode are calculated at various pressures at room temperature for the cubic-tetragonal transition (P-c = 9.5 GPa) in SrTiO3. This calculation is performed using the observed volume data through the mode Gruneisen parameters of A(1g) and B-1 which vary with pressure, by fitting to the experimental wavenumbers in this crystalline system. Calculated Raman shifts are then used as order parameters to predict the pressure dependence of the damping constant and the inverse relaxation time for the cubic-tetragonal transition in SrTiO3. Our predictions from the pseudospin-phonon coupling and the energy fluctuation models can be compared with the experimental measurements when available in the literature.
Subject Keywords
Raman Wavenumber
,
Mode Gruneisen Parameter
,
Damping Constant
,
İnverse Relaxation Time
,
Srtio3
URI
https://hdl.handle.net/11511/47784
Journal
TURKISH JOURNAL OF PHYSICS
DOI
https://doi.org/10.3906/fiz-1705-21
Collections
Department of Physics, Article