Theoretical and experimental considerations on poly(dihalophenylene oxide)s

Date

1988

Author

Kisakürek, Duygu

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The decomposition of copper(II) trihalophenoxides in acetonitrile yields poly(dihalophenylene oxide)s. A 1H n.m.r. study has shown that a bromine atom in the 4‐position of the trihalophenoxides results in polymers having higher linearity. Various dynamic and static methods, within the framework of Hückel molecular orbital theory, have been used to explain the product distribution.

Subject Keywords

General Engineering, General Materials Science

URI

https://hdl.handle.net/11511/51968

Journal

British Polymer Journal

DOI

https://doi.org/10.1002/pi.4980200208

Collections

Department of Chemistry, Article

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Further experimental considerations on poly(dihalophenylene oxide) Türker, Lemi; Kısakürek, Duygu (Wiley, 1989) The decomposition of copper(II) 2,6‐dibromo‐4‐chlorophenoxide in acetonitrile yields poly(dihalophenylene oxide). 1H NMR study revealed that 1,4‐catenation was favoured over 1,2‐catenation, leading to higher linearity in the structure.
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Citation Formats

D. Kisakürek, “Theoretical and experimental considerations on poly(dihalophenylene oxide)s,” British Polymer Journal, pp. 131–141, 1988, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/51968.