The effects of potassium and rubidium hydroxide on the alkali-silica reaction

Date

2003-11-01

Author

Shomglin, K
Turanlı, Lutfullah
Wenk, HR
Monteiro, PJM
Sposito, G

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

227
views

0
downloads

Expansion of mortar specimens prepared with an aggregate of mylonite from the Santa Rosa mylonite zone in southern California was studied to investigate the effect of different alkali ions on the alkali-silica reaction in concrete. The expansion tests indicate that mortar has a greater expansion when subjected to a sodium hydroxide bath than in a sodium-potassium-rubidium hydroxide bath. Electron probe microanalysis (EPMA) of mortar bars at early ages show that rubidium ions, used as tracer, were present throughout the sample by the third day of exposure. The analysis also shows a high concentration of rubidium in silica gel from mortar bars exposed to bath solutions containing rubidium. The results suggest that expansion of mortar bars using ASTM C 1260 does not depend on the diffusion of alkali ions. The results indicate that the expansion of alkali-silica gel depends on the type of alkali ions present. Alkali-silica gel containing rubidium shows a lower concentration of calcium, suggesting competition for the same sites.

Subject Keywords

General Materials Science, Building and Construction

URI

https://hdl.handle.net/11511/52324

Journal

CEMENT AND CONCRETE RESEARCH

DOI

https://doi.org/10.1016/s0008-8846(03)00204-7

Collections

Graduate School of Natural and Applied Sciences, Article

Suggestions

OpenMETU
Core

Synthesis of copolymers of methoxy polyethylene glycol acrylate and 2-acrylamido-2-methyl-1-propanesulfonic acid: Its characterization and application as superplasticizer in concrete Buyukyagci, Arzu; Tuzcu, Goezde; Aras, Leyla (Elsevier BV, 2009-07-01) Water-soluble copolymers of methoxy polyethylene glycol acrylate (mPEGA) and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) were synthesized by free radicalic polymerization and evaluated as slump-retaining dispersant for cement particles. The slump-retaining effect of the synthesized copolymers was studied in terms of reaction pH, composition, and molecular weight of mPEG side chains. mPEG grafted copolymers (mPEGA-co-AMPS) were characterized by FTIR, H-1 NMR. In this study, dilute solution viscometry...
Effect of material characteristics on the properties of blended cements containing high volumes of natural pozzolans Turanlı, Lutfullah; Uzal, B; Bektas, F (Elsevier BV, 2004-12-01) The effect of three different natural pozzolans from Turkish deposits on the properties of blended cements produced by intergrinding cement clinker with a high volume of natural pozzolan (55 wt.% of the cementitious material) was investigated. The particle size distribution of blended cements, setting time, heat of hydration, and compressive strength of blended cement mortars were determined. Experimental results showed that the hardness of the pozzolanic material strongly influenced the particle size distr...
Studies on blended cements containing a high volume of natural pozzolans Uzal, B; Turanlı, Lutfullah (Elsevier BV, 2003-11-01) This paper presents the results of an investigation on the characteristics of laboratory-produced blended portland cements containing 55% by weight volcanic tuffs from Turkey. Volcanic tuffs from two different resources were used. Using different grinding times, particle size distribution, setting time, compressive strength, and alkali-silica activity of the blended cements were investigated and compared with reference portland cements ground for the same time period. For the compressive strength test, a su...
Determination of the elastic properties of amorphous materials: Case study of alkali-silica reaction gel Moon, Juhyuk; Speziale, Sergio; Akgül, Çağla; KALKAN, BORA; Clark, Simon M; Monteiro, Paulo JM (Elsevier BV, 2013-12-01) The gel formed during alkali-silica reaction (ASR) can lead to cracking and deterioration of a concrete structure. The elastic properties of the ASR gel using X-ray absorption and Brillouin spectroscopy measurements are reported. X-ray absorption was used to determine the density of the gel as a function of pressure, and the result yields an isothermal bulk modulus of 33 +/- 2 GPa. Brillouin spectroscopy was applied to measure isentropic bulk (24.9-34.0 GPa) and shear moduli (8.7-10.1 GPa) of the gel. The r...
Influence of the shape and roughness of inclusions on the rheological properties of a cementitious suspension Erdoğan, Sinan Turhan; Ferraris, C. F.; Fowler, D. W. (Elsevier BV, 2008-05-01) The influence of particle shape and surface roughness on the rheological properties of cementitious composites (cement paste plus coarse and fine particles) was investigated for mixtures of mortars and laboratory-made aggregates. The coarse particles were monosized spheres and cubes made from mortar, and monosized glass spheres, uncoated or roughened. The fine particles were uncoated or roughened monosized glass mini-spheres. The coarse particle mixtures were tested with a concrete rheometer to investigate ...

Citation Formats

K. Shomglin, L. Turanlı, H. Wenk, P. Monteiro, and G. Sposito, “The effects of potassium and rubidium hydroxide on the alkali-silica reaction,” CEMENT AND CONCRETE RESEARCH, pp. 1825–1830, 2003, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/52324.