ELECTROINITIATED CATIONIC COPOLYMERIZATION OF 4-BROMOSTYRENE AND ALPHA-METHYLSTYRENE IN THE PRESENCE OF ULTRASONIC VIBRATION

Date

1987-01-01

Author

EREN, S
Toppare, Levent Kamil
Akbulut, Ural

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https://hdl.handle.net/11511/52576

Journal

POLYMER COMMUNICATIONS

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Department of Chemistry, Article

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ELECTROINITIATED POLYMERIZATION OF HALOPHENOLS - ELECTROINITIATION POTENTIAL LUMO RELATIONS TURKER, L; KISAKUREK, D; SEN, S; Toppare, Levent Kamil; Akbulut, Ural (Wiley, 1988-11-01) Electroinitiated polymerizations can be carried out by direct electron transfer via constant potential electrolysis.1–3 In doing so, the anodic (Ep, a) and the cathodic (Ep, c) potentials of the monomers must be measured by cyclic voltammetry. The cathodic peak potentials of halophenols were measured on Pt0 electrode versus Ag0/Ag+ in acetonitrile. Electroinitiated polymerization of bis(pyridine), bis(4‐chloro‐2,6‐dibromophenoxide) copper (II) complex was studied in dimethylformamide‐tetrabutylammonium flu...
ELECTROINITIATED POLYMERIZATION OF ACRYLAMIDE BY DIRECT ELECTRON-TRANSFER HACIOGLU, B; Akbulut, Ural; Toppare, Levent Kamil (Wiley, 1989-10-01) Electroinitiated polymerization of acrylamide was carried out in acetonitrile–tetrabutylammonium fluoroborate by electrolytic reduction of monomer. It was shown by cyclic voltammetry that direct electron transfer from the cathode to the monomer can be achieved in this solvent–electrolyte system. Reduction peak potentials measured by cyclic voltammetry indicated that sodium salts will interfere with such a mechanism. Since the reduction peak potential of sodium salt and dimethylformamide are found to be lowe...
ELECTROINITIATED POLYMERIZATION OF MALEIC-ANHYDRIDE BY DIRECT ELECTRON-TRANSFER Akbulut, Ural (Wiley, 1991-02-01) Controlled potential electrolysis was employed to accomplish homopolymerization of maleic anhydride, by direct electron transfer. The solvent used in the polymerization studies was acetonitrile-dimethylformamide mixture (1:1) with the supporting electrolyte tetrabutylammonium tetra fluoroborate. A brown paramagnetic polymer was obtained from the catholyte, upon electroreduction of monomer.
ELECTROINITIATED COPOLYMERIZATION OF ISOPRENE WITH INDENE KHURSHID, A; Toppare, Levent Kamil; Akbulut, Ural (1987-09-01)

Citation Formats

S. EREN, L. K. Toppare, and U. Akbulut, “ELECTROINITIATED CATIONIC COPOLYMERIZATION OF 4-BROMOSTYRENE AND ALPHA-METHYLSTYRENE IN THE PRESENCE OF ULTRASONIC VIBRATION,” POLYMER COMMUNICATIONS, pp. 36–38, 1987, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/52576.