AN EFFICIENT BUTENOLIDE ANNULATION VIA ALPHA'-CHLOROACETOXYLATION OF ENONES USING MANGANESE(III) ACETATE AND CHLOROACETIC ACID

Date

1991-09-01

Author

DEMIR, AS
AKGUN, H
Tanyeli, Cihangir
SAYRAC, T
WATT, DS

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The alpha'-chloroacetoxylation of alpha,-beta-unsaturated ketones using manganese(III) acetate and chloroacetic acid followed by Arbuzov reaction and intramolecular Horner-Emmons olefination provided a convenient synthesis of annulated 2-buten-4-olides.

Subject Keywords

CARBOXYLIC-ACIDS, FURAN SYNTHESIS, COMBINATION, DERIVATIVES, OXIDATION

URI

https://hdl.handle.net/11511/52650

Journal

SYNTHESIS-STUTTGART

Collections

Department of Chemistry, Article

Citation Formats

A. DEMIR, H. AKGUN, C. Tanyeli, T. SAYRAC, and D. WATT, “AN EFFICIENT BUTENOLIDE ANNULATION VIA ALPHA’-CHLOROACETOXYLATION OF ENONES USING MANGANESE(III) ACETATE AND CHLOROACETIC ACID,” SYNTHESIS-STUTTGART, no. 9, pp. 719–721, 1991, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/52650.