Temperature and pressure dependence of the Raman frequency shifts in anthracene

Date

2016-08-01

Author

Ozdemir, H.
Yurtseven, Hasan Hamit

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In this study, the Raman frequency shifts of phonons and vibrons of crystalline anthracene as functions of temperature (at zero pressure) and pressure (at ambient temperature) have-been calculated using the experimental volume data from the literature. This calculation is performed for six phonons and nine vibrons through the mode Gruneisen parameters which have been determined from the Raman frequency and volume data at various pressures. Our predicted Raman frequencies of the phonon modes decrease with increasing temperature (zero pressure) linearly, whereas they increase with increasing pressure (ambient temperature) nonlinearly, as observed experimentally for anthracene. For vibrons, we find that the Raman frequencies are almost independent of temperature and pressure in this crystalline system.

Subject Keywords

Raman frequency shifts, Mode Gruneisen parameter, Anthracene

URI

https://hdl.handle.net/11511/53314

Journal

INDIAN JOURNAL OF PURE & APPLIED PHYSICS

Collections

Department of Physics, Article

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Citation Formats

H. Ozdemir and H. H. Yurtseven, “Temperature and pressure dependence of the Raman frequency shifts in anthracene,” INDIAN JOURNAL OF PURE & APPLIED PHYSICS, pp. 489–494, 2016, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/53314.