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Addition of dibromocarbene to cyclobutene: characterisation and mechanism of formation of the products
Date
2004-10-01
Author
Algi, Fatih
Hokelek, Tuncer
Balcı, Metin
Metadata
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Cyclobutene reacted with dibromocarbene in solution to give 1,5-dibromocyclopent-1-ene (9), 1,2,6, 6-tetrabromobicyclo[3.1.0]hexane (10), and 1,2,3,6-tetrabromocyclohex-1-ene (11), in a ratio of 1:4:8, respectively. Compounds 10 and 11 were found to be formed from a second carbene addition and rearrangement under the given reaction conditions.
Subject Keywords
Carbene
,
Carbene addition
,
Cyclopropane
,
Cyclobutene
URI
https://hdl.handle.net/11511/55700
Journal
JOURNAL OF CHEMICAL RESEARCH
DOI
https://doi.org/10.3184/0308234043431906
Collections
Graduate School of Natural and Applied Sciences, Article
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F. Algi, T. Hokelek, and M. Balcı, “Addition of dibromocarbene to cyclobutene: characterisation and mechanism of formation of the products,”
JOURNAL OF CHEMICAL RESEARCH
, pp. 658–660, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/55700.