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THE EFFECT OF ALKYL-GROUPS ON CARBANION STABILITY .1. INTERACTION OF SMALL RINGS WITH ADJACENT CARBANION CENTERS
Date
1992-02-01
Author
BALCIOGLU, N
SEVIN, F
EVIN, O
Peynircioğlu, Nihad Bekir
Metadata
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Relative kinetic acidity measurements have shown that the cyclobutyl group has the ability to stabilize an adjacent carbanion center similar to vinyl and cyclopropyl groups, although to a lesser extent. The results of semiempirical calculations (MNDO) covering all the mentioned substituents, including the isopropyl group correlate well with the experimentally determined relative kinetic acidities.
Subject Keywords
Carbanion Stability
,
Kinetic Acidity Measurement
,
Mndo Calculations
,
Quantum Mechanics
,
Small Ring Effects
,
Spectroscopy
,
Nuclear Magnetic Resonance
URI
https://hdl.handle.net/11511/56378
Journal
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS
DOI
https://doi.org/10.1002/bbpc.19920960206
Collections
Department of Chemistry, Article
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N. BALCIOGLU, F. SEVIN, O. EVIN, and N. B. Peynircioğlu, “THE EFFECT OF ALKYL-GROUPS ON CARBANION STABILITY .1. INTERACTION OF SMALL RINGS WITH ADJACENT CARBANION CENTERS,”
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS
, pp. 139–142, 1992, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/56378.