THE EFFECT OF ALKYL-GROUPS ON CARBANION STABILITY .1. INTERACTION OF SMALL RINGS WITH ADJACENT CARBANION CENTERS

Date

1992-02-01

Author

BALCIOGLU, N
SEVIN, F
EVIN, O
Peynircioğlu, Nihad Bekir

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Relative kinetic acidity measurements have shown that the cyclobutyl group has the ability to stabilize an adjacent carbanion center similar to vinyl and cyclopropyl groups, although to a lesser extent. The results of semiempirical calculations (MNDO) covering all the mentioned substituents, including the isopropyl group correlate well with the experimentally determined relative kinetic acidities.

Subject Keywords

Carbanion Stability, Kinetic Acidity Measurement, Mndo Calculations, Quantum Mechanics, Small Ring Effects, Spectroscopy, Nuclear Magnetic Resonance

URI

https://hdl.handle.net/11511/56378

Journal

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS

DOI

https://doi.org/10.1002/bbpc.19920960206

Collections

Department of Chemistry, Article

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Citation Formats

N. BALCIOGLU, F. SEVIN, O. EVIN, and N. B. Peynircioğlu, “THE EFFECT OF ALKYL-GROUPS ON CARBANION STABILITY .1. INTERACTION OF SMALL RINGS WITH ADJACENT CARBANION CENTERS,” BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, pp. 139–142, 1992, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/56378.