Enzymatic synthesis of benzoin in supercritical carbon dioxide

2007-07-01
Celebi, Nuray
Yildiz, Nuray
Demir, Ayhan Sıtkı
Calimli, Ayla
Enantioselective enzymatic hydrolysis of benzoyl-benzoin catalyzed by Candida cylindracea (CCL) lipase was carried out in SCCO2. It was found that CCL lipase enantioselectively hydrolyzed the (R)-benzoin. The enantiomeric excess of product (ee(p)) was maximized at 35 degrees C near the critical region 90 bar and obtained 61.3% at a 50% conversion. CCL did not catalyze the reaction in an atmospherical condition.
JOURNAL OF SUPERCRITICAL FLUIDS

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Citation Formats
N. Celebi, N. Yildiz, A. S. Demir, and A. Calimli, “Enzymatic synthesis of benzoin in supercritical carbon dioxide,” JOURNAL OF SUPERCRITICAL FLUIDS, pp. 386–390, 2007, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/57697.