Theoretical electronic spectra for models having ferredoxin-core

Date

2002-10-31

Author

Türker, Burhan Lemi

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Ferredoxin-core model [Fe4S4] type iron-sulfur cluster having four cysteine moieties in the amide form, has been considered theoretically for electronic excitation spectrum. The neutral as well as the -/+ 2 charged forms of the model have been investigated within the restrictions of ZINDO/S (RHF) approach involving configuration interaction considerations. The charged forms, especially the negative one exhibited some bathochromic shift and hyperchromic effect.

Subject Keywords

UV-Vis spectra, Ferredoxin, Ferrodoxin, Photosystem, Iron-sulfur clusters

URI

https://hdl.handle.net/11511/62388

Journal

JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM

DOI

https://doi.org/10.1016/s0166-1280(02)00415-3

Collections

Department of Chemistry, Article

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Citation Formats

B. L. Türker, “Theoretical electronic spectra for models having ferredoxin-core,” JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, pp. 133–139, 2002, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/62388.