Oxidative dehydrogenation of ethane over a monolith coated by molybdenum-vanadium-niobium mixed-oxide catalyst

2003-10-01
Karamullaoglu, G
Doğu, Timur
Oxidative dehydrogenation of ethane to ethylene was investigated using Mo0.71V0.21N0.08 mixed-oxide catalyst. in powder form and coated over a monolith. At 570degreesC and with a feed stream containing an O-2/C2H6 mole ratio of one. ethylene selectivity value reaching to 96% was obtained Lit a conversion level of about 5% with the monolith-supported catalyst. DRIFTS studies indicated the presence of adsorbed ethoxide species. The proposed reaction scheme for the production of ethylene includes the elimination of beta-hydrogen of adsorbed species by the lattice oxygen.
CHEMICAL ENGINEERING COMMUNICATIONS

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Citation Formats
G. Karamullaoglu and T. Doğu, “Oxidative dehydrogenation of ethane over a monolith coated by molybdenum-vanadium-niobium mixed-oxide catalyst,” CHEMICAL ENGINEERING COMMUNICATIONS, pp. 1427–1438, 2003, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/62520.