Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
Sol-gel Approaches for Elaboration of Polyol Dehydrogenase-Based Bioelectrodes
Date
2013-01-01
Author
Urbanova, Veronika
Kohring, Gert-Wieland
Klein, Tobias
Wang, Zhijie
Mert, Olcay
Emrullahoglu, Mustafa
Buran, Kerem
Demir, Ayhan Gürbüz
Etienne, Mathieu
Walcarius, Alain
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
180
views
0
downloads
Cite This
This review describes the input of sol-gel chemistry to the immobilization of polyol dehydrogenases on electrodes, for applications in bioelectrocatalysis. The polyol dehydrogenases are described and their application for biosensing, biofuel cell and electrosynthesis are briefly discussed. The immobilization of proteins via sol-gel approaches is described, including a discussion on the difficulty to maintain the activity of proteins in a silica matrix and the strategies developed to offer a proper environment to the proteins by developing optimal organic-inorganic hybrid materials. Finally, the co-immobilization of the NAD(+) co-factor and of mediators for the elaboration of reagentless devices is presented, based on published and original data. All-in-all, sol-gel approaches appear to be a very promising for development of original electrochemical applications involving dehydrogenases in near future.
Subject Keywords
Physical and Theoretical Chemistry
URI
https://hdl.handle.net/11511/63057
Journal
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS
DOI
https://doi.org/10.1524/zpch.2013.0324
Collections
Department of Educational Sciences, Article
Suggestions
OpenMETU
Core
INTRAZEOLITE SEMICONDUCTORS - NA-23 MAS NMR, TL+ LUMINESCENCE QUENCHING, AND FAR-IR STUDIES OF ACID-BASE PRECURSOR CHEMISTRY IN ZEOLITE-Y
MCMURRAY, L; HOLMES, AJ; KUPERMAN, A; OZIN, GA; Özkar, Saim (American Chemical Society (ACS), 1991-11-01)
Proton-loaded zeolites, prepared from fully dehydrated zeolites and gaseous, anhydrous Bronsted acids, represent an important step in the synthesis of intrazeolite semiconductor quantum supralattices. Adsorption-induced Na-23 MAS NMR chemical shifts, far-IR Na+ and Tl+ translatory mode frequency shifts, and Tl+ luminescence quenching effects were chosen as probes of cation-anion interaction in these materials. Samples of zeolite Y with various loadings of Tl+ were prepared via aqueous ion-exchange techniq...
INTRAZEOLITE PHOTOTOPOTAXY - EXAFS ANALYSIS OF PRECURSOR 8(W(CO)6)-NA56Y AND PHOTOOXIDATION PRODUCTS 16(WO3)-NA56Y AND 28(WO3)-NA56Y
MOLLER, K; BEIN, T; Özkar, Saim; OZIN, GA (American Chemical Society (ACS), 1991-06-01)
The intrazeolite photooxidation chemistry of alpha-cage encapsulated hexacarbonyltungsten(0) in Na56Y with O2, denoted n{W(CO)6}-Na56Y/O2/hv, which has previously been shown to provide a novel synthetic pathway to alpha-cage located tungsten(VI) oxide, denoted n(WO3)-Na56Y, is now the subject of an extended X-ray absorption fine structure (EXAFS) analysis. The EXAFS data of a precursor 8{W(CO)6}Na56Y, which contains on average one W(CO)6 per alpha-cage shows that the W(CO)6 guest maintains its structural in...
Bosonic helium clusters doped by alkali metal cations: interaction forces and analysis of their most stable structures
Marinetti, F.; Coccia, E.; Bodo, E.; Gianturco, F. A.; Yurtsever, E.; Yurtsever, M.; Yıldırım, Erol (Springer Science and Business Media LLC, 2007-07-01)
Ab initio potentials are computed for alkali metal cationic partners interacting with He-4 and an overall many-body potential is constructed for each of the ionic dopants in helium clusters. The structures are then obtained via a genetic algorithm approach and results compared with Basin-Hopping Monte Carlo simulations. The classical arrangements are analyzed and quantum effects discussed in comparison with what has been found with Diffusion Monte Carlo calculations. Further corrections to the classical pic...
PM3 treatment of some endohedrally Se and H-2 doped C-60 systems
Türker, Burhan Lemi (Elsevier BV, 2005-03-17)
Certain endohedrally Se and hydrogen doped C-60 systems, (Se + nH(2)) @ C-60 have been quantum chemically investigated by using PM3 method at the level of RHF approach. The composite structures are found to be stable but endothermic in nature. The Se@C-60 system is found to be unable to accommodate more than nine hydrogen molecules.
Dielectric Properties of Ethanol and Gasoline Mixtures by Terahertz Spectroscopy and an Effective Method for Determination of Ethanol Content of Gasoline
ARIK, Enis; Altan, Hakan; Esentürk, Okan (American Chemical Society (ACS), 2014-05-01)
Investigation of frequency dependent permittivity of mixture solutions provides information on the role of intermolecular interactions on relaxation processes of solvent and solute molecules. In this study the dielectric properties of ethanol/gasoline mixtures in the terahertz spectral region are investigated. Frequency dependent absorption coefficients, refractive indices, and complex permittivities of pure ethanol and gasoline, and their mixtures at varying ethanol volume percentages (v/v %) are reported....
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
V. Urbanova et al., “Sol-gel Approaches for Elaboration of Polyol Dehydrogenase-Based Bioelectrodes,”
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS
, pp. 667–689, 2013, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/63057.