Chain-extended bismaleimides .1. Preparation and characterization of maleimide-terminated resins

Yerlikaya, Z
Oktem, Z
Bayramlı, Erdal
Starting from aromatic diamines, a series of bismaleimides (BMIs) and maleimide-terminated structural resins were prepared in solution and characterized. Maleimide-terminated resins were prepared through Michael addition reaction with 3/2 molar ratio of bismaleimide and aromatic diamine as reactants. The structural analysis was performed by FTIR and H-1-NMR spectroscopy. Thermal properties are investigated by TGA, DTA, and DSC. Number-average molecular-weights of the resins were determined by cryoscopy. The presence of methylene (-CH2-) and ether (-O-) groups in the starting materials affect the reactivity and the degree of chain extension of the resins. From the viscosity measurements it was also found that thermal polymerization of BMIs could be taking place together with the Michael addition. (C) 1996 John Wiley & Sons, Inc.


TINCER, T; COSKUN, M (1993-10-01)
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SACAN, L; Çırpan, Ali; CAMURLU, P; Toppare, Levent Kamil (Elsevier BV, 2006-02-01)
The homopolymer and copolymer of succinic acid bis-(2-thiophen-3-yl-ethyl)ester with thiophene were achieved via constant potential electrolysis in the presence of tetrabutylammonium tetrafluoroborate as the supporting electrolyte, and acetonitrile/borontrifluoride ethylether (ACN/BFEE) (10:2 v/v) solvent mixture. The characterizations of both homopolymer (PSATE) and copolymer P(SATE-co-Th) were achieved by various techniques including cyclic voltammetry (CV), Fr-IR, scanning electron microscopy (SEM) and U...
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Saki, N; Dinc, T; Akkaya, EU (2006-03-13)
Using a rigid xanthene scaffold, a series of boradiazaindacene derivatives were synthesized. In some of these compounds, two boradiazaindacene derivatives were placed cofacially, resulting in significant inter-chromophoric interactions, including excimer emission. A simple modification of boradiazaindacene structure leads to formation of an ICT dye, which has distinct spectral properties. Energy transfer between two BODIPY dyes was demonstrated as well. In addition, the spectral properties of ICT dye can be...
Citation Formats
Z. Yerlikaya, Z. Oktem, and E. Bayramlı, “Chain-extended bismaleimides .1. Preparation and characterization of maleimide-terminated resins,” JOURNAL OF APPLIED POLYMER SCIENCE, pp. 165–171, 1996, Accessed: 00, 2020. [Online]. Available: