Significance of the excitonic intensity borrowing in the J-/H-aggregates of bacteriochlorophylls/chlorophylls

2006-02-01
Gulen, D
A quantitative analysis of the excitonic intensity borrowing for the J-/H-aggregates of the bacteriochlorophylls/chlorophylls (BChls/Chls) in specific, and of porphyrins in general, is presented. The analysis is based on the argument that the mixing between the two energetically well-separated bands, such as the Q and B bands of BChls/Chls, should be considered important if the aggregated system possesses an excitonic superstate. A remarkably simple explanation of the significance of the excitonic intensity borrowing is given: superhyperchromism is manifested by the mediation of interband coupling between the superstates in the two well- separated bands of such aggregates. A comprehensive discussion on the significance of superhyperchromism and on its size-dependence is provided in connection with its effects on the absorption spectra of the BChl/Chl J- and H-aggregates.

Citation Formats
D. Gulen, “Significance of the excitonic intensity borrowing in the J-/H-aggregates of bacteriochlorophylls/chlorophylls,” PHOTOSYNTHESIS RESEARCH, vol. 87, no. 2, pp. 205–214, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/63557.