Synthesis and Characterization of Polypyrrole Nanoparticles and Their Nanocomposites with Poly(propylene)

Sevil, Baytekin
Zuhal, Kucukyavuz
Conducting polypyrrole (PPy) nanoparticles were synthesized via microemulsion polymerization. PP/PPy nanocomposites were prepared by melt-mixing of polypyrrole with polypropylene (PP) and processed with injection molding. Tensile tests have revealed that increasing amount of PPy increased the strength and the stiffness of the nanocomposite while limiting the elongation of PP. Thermal gravimetric analysis has showed that incorporation of PPy nanoparticles has improved the thermal stability of the nanocomposites. Increasing amount of PPy nanoparticles increases the conductivity of nonconductive PP up to 2,4.10(-4) Scm(-1). The same techniques were used to characterize nanocomposites containing 2% w dispersant. Composites prepared with dispersant have involved smaller dimension PPy nanoparticles and exhibited improvement in some mechanical and thermal properties.


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New pi-conjugated polymers containing dithieno(3,2-b: 2',3'-d) pyrrole (DTP) were successfully synthesized via electropolymerization. The effect of structural differences on the electrochemical and optoelectronic properties of the 4-[4H-dithieno(3,2-b: 2',3'-d) pyrrol-4-yl] aniline (DTP-aryl-NH2), 10-[4H-dithiyeno(3,2-b: 2',3'-d) pirol-4-il] dekan-1-amine (DTP-alkyl-NH2), and 1,10-bis[4H-dithieno(3,2-b:2',3'-d) pyrrol-4-yl] decane (DTP-alkyl-DTP) were investigated. The corresponding polymers were characteri...
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Citation Formats
B. Sevil and K. Zuhal, “Synthesis and Characterization of Polypyrrole Nanoparticles and Their Nanocomposites with Poly(propylene),” 2009, vol. 295, p. 59, Accessed: 00, 2020. [Online]. Available: