SYNTHESIS OF BLOCK COPOLYMERS VIA ANION-TO-RADICAL TRANSFORMATION

1992-10-01
HAZER, B
CAKMAK, I
KUCUKYAVUZ, S
NUGAY, T
Synthesis of (methyl methacrylate)-styrene block copolymers was carried out using anion-to-radical transformation. For this purpose, living polystyryl anion, prepared by using a new anionic difunctional initiator, 1,5-di(2-(3,3-dimethyl butyl-1-lithio)naphthalene, was terminated by the addition of 4,4'-bromomethyl dibenzoyl peroxide. Polystyrene samples having peroxide terminal groups were then used as initiators in the polymerization of methyl methacrylate. Block copolymers were characterized by spectroscopic and fractional precipitation methods.
EUROPEAN POLYMER JOURNAL

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Citation Formats
B. HAZER, I. CAKMAK, S. KUCUKYAVUZ, and T. NUGAY, “SYNTHESIS OF BLOCK COPOLYMERS VIA ANION-TO-RADICAL TRANSFORMATION,” EUROPEAN POLYMER JOURNAL, pp. 1295–1297, 1992, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/67878.